Extending the Second-Generation Phosphorus–Nitrogen PN3-Pincer Ligand Family through Ligand Post-Modification

Mei Hui Huang; Jinsong Hu; Kuo Wei Huang

doi:10.1002/jccs.201700205

Extending the Second-Generation Phosphorus–Nitrogen PN³-Pincer Ligand Family through Ligand Post-Modification

Mei Hui Huang, Jinsong Hu, Kuo Wei Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A series of air-stable nickel complexes containing triazine-based PN³P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN³P^*NiCl complex (3) could be converted into a new class of diimine–traizine PN³P-pincer nickel complexes.

Original language	English (US)
Pages (from-to)	60-64
Number of pages	5
Journal	Journal of the Chinese Chemical Society
Volume	65
Issue number	1
DOIs	https://doi.org/10.1002/jccs.201700205
State	Published - Jan 2018

Bibliographical note

Publisher Copyright:
© 2017 The Chemical Society Located in Taipei & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

Coordination chemistry
Ligand post-modification
Nickel
Pincer complex

ASJC Scopus subject areas

General Chemistry

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10.1002/jccs.201700205

Cite this

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title = "Extending the Second-Generation Phosphorus–Nitrogen PN3-Pincer Ligand Family through Ligand Post-Modification",

abstract = "A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.",

keywords = "Coordination chemistry, Ligand post-modification, Nickel, Pincer complex",

author = "Huang, {Mei Hui} and Jinsong Hu and Huang, {Kuo Wei}",

note = "Publisher Copyright: {\textcopyright} 2017 The Chemical Society Located in Taipei & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2018",

month = jan,

doi = "10.1002/jccs.201700205",

language = "English (US)",

volume = "65",

pages = "60--64",

journal = "Journal of the Chinese Chemical Society",

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T1 - Extending the Second-Generation Phosphorus–Nitrogen PN3-Pincer Ligand Family through Ligand Post-Modification

AU - Huang, Mei Hui

AU - Hu, Jinsong

AU - Huang, Kuo Wei

PY - 2018/1

Y1 - 2018/1

N2 - A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

AB - A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

KW - Coordination chemistry

KW - Ligand post-modification

KW - Nickel

KW - Pincer complex

UR - http://www.scopus.com/inward/record.url?scp=85030456350&partnerID=8YFLogxK

U2 - 10.1002/jccs.201700205

DO - 10.1002/jccs.201700205

M3 - Article

AN - SCOPUS:85030456350

SN - 0009-4536

VL - 65

SP - 60

EP - 64

JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

IS - 1

ER -

Extending the Second-Generation Phosphorus–Nitrogen PN³-Pincer Ligand Family through Ligand Post-Modification

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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CCDC 1866911: Experimental Crystal Structure Determination : chloro-{N,N'-(6-methyl-1,3,5-triazine-2,4-diyl)bis[P,P-di-t-butyl(phosphinous amide)]}-nickel chloride unknown solvate

CCDC 1866912: Experimental Crystal Structure Determination : chloro-(P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-4-methyl-1,3,5-triazin-2(1H)-ylidene}phosphinous amidato)-nickel chloroform solvate

CCDC 1866909: Experimental Crystal Structure Determination : N,N'-(6-methyl-1,3,5-triazine-2,4-diyl)bis[P,P-di-t-butyl(phosphinous amide)] dihydrate

Cite this

Extending the Second-Generation Phosphorus–Nitrogen PN3-Pincer Ligand Family through Ligand Post-Modification

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1866911: Experimental Crystal Structure Determination : chloro-{N,N'-(6-methyl-1,3,5-triazine-2,4-diyl)bis[P,P-di-t-butyl(phosphinous amide)]}-nickel chloride unknown solvate

CCDC 1866912: Experimental Crystal Structure Determination : chloro-(P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-4-methyl-1,3,5-triazin-2(1H)-ylidene}phosphinous amidato)-nickel chloroform solvate

CCDC 1866909: Experimental Crystal Structure Determination : N,N'-(6-methyl-1,3,5-triazine-2,4-diyl)bis[P,P-di-t-butyl(phosphinous amide)] dihydrate

Cite this

Extending the Second-Generation Phosphorus–Nitrogen PN³-Pincer Ligand Family through Ligand Post-Modification