Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

Marina O. Barsukova; Sergey A. Sapchenko; Konstantin A. Kovalenko; Denis G. Samsonenko; Andrei S. Potapov; Danil N. Dybtsev; Vladimir P. Fedin

doi:10.1039/c8nj00494c

Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

Marina O. Barsukova, Sergey A. Sapchenko^*, Konstantin A. Kovalenko, Denis G. Samsonenko, Andrei S. Potapov, Danil N. Dybtsev, Vladimir P. Fedin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Six isoreticular metal-organic frameworks (MOFs) based on zinc, cadmium and cobalt ions, 4,4′-stilbenedicarboxylic acid and the flexible ligands 1,4-bis(imidazol-1-yl)butane and 1,6-bis(imidazol-1-yl)hexane were prepared. The synergistic effect coming from the assembly of stilbenedicarboxylate and imidazolyl ligands led to multifunctional materials with excellent photoluminescence and good sorption capacity for carbon dioxide and iodine vapor.

Original language	English (US)
Pages (from-to)	6408-6415
Number of pages	8
Journal	New Journal of Chemistry
Volume	42
Issue number	8
DOIs	https://doi.org/10.1039/c8nj00494c
State	Published - 2018

Bibliographical note

Funding Information:
Work on the synthesis of ligands C4 and C6 was supported by the Russian Science Foundation, Grant No. 15-13-10023. Research on the synthesis of compounds 1–6, determination of their structures and the investigation of the sorption and luminescence properties was supported by the Russian Science Foundation, Grant No. 14-23-00013. The authors are grateful to Dr A. A. Ryadun for the luminescence studies.

Publisher Copyright:
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

ASJC Scopus subject areas

Catalysis
General Chemistry
Materials Chemistry

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10.1039/c8nj00494c

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Barsukova, M. O., Sapchenko, S. A., Kovalenko, K. A., Samsonenko, D. G., Potapov, A. S., Dybtsev, D. N., & Fedin, V. P. (2018). Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers? New Journal of Chemistry, 42(8), 6408-6415. https://doi.org/10.1039/c8nj00494c

@article{40ad833b3fcd4e968d0615f68f311e86,

title = "Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?",

abstract = "Six isoreticular metal-organic frameworks (MOFs) based on zinc, cadmium and cobalt ions, 4,4′-stilbenedicarboxylic acid and the flexible ligands 1,4-bis(imidazol-1-yl)butane and 1,6-bis(imidazol-1-yl)hexane were prepared. The synergistic effect coming from the assembly of stilbenedicarboxylate and imidazolyl ligands led to multifunctional materials with excellent photoluminescence and good sorption capacity for carbon dioxide and iodine vapor.",

author = "Barsukova, {Marina O.} and Sapchenko, {Sergey A.} and Kovalenko, {Konstantin A.} and Samsonenko, {Denis G.} and Potapov, {Andrei S.} and Dybtsev, {Danil N.} and Fedin, {Vladimir P.}",

note = "Funding Information: Work on the synthesis of ligands C4 and C6 was supported by the Russian Science Foundation, Grant No. 15-13-10023. Research on the synthesis of compounds 1–6, determination of their structures and the investigation of the sorption and luminescence properties was supported by the Russian Science Foundation, Grant No. 14-23-00013. The authors are grateful to Dr A. A. Ryadun for the luminescence studies. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",

year = "2018",

doi = "10.1039/c8nj00494c",

language = "English (US)",

volume = "42",

pages = "6408--6415",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "8",

}

Barsukova, MO, Sapchenko, SA, Kovalenko, KA, Samsonenko, DG, Potapov, AS, Dybtsev, DN & Fedin, VP 2018, 'Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?', New Journal of Chemistry, vol. 42, no. 8, pp. 6408-6415. https://doi.org/10.1039/c8nj00494c

Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers? / Barsukova, Marina O.; Sapchenko, Sergey A.; Kovalenko, Konstantin A. et al.
In: New Journal of Chemistry, Vol. 42, No. 8, 2018, p. 6408-6415.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Exploring the multifunctionality in metal-organic framework materials

T2 - How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

AU - Barsukova, Marina O.

AU - Sapchenko, Sergey A.

AU - Kovalenko, Konstantin A.

AU - Samsonenko, Denis G.

AU - Potapov, Andrei S.

AU - Dybtsev, Danil N.

AU - Fedin, Vladimir P.

N1 - Funding Information: Work on the synthesis of ligands C4 and C6 was supported by the Russian Science Foundation, Grant No. 15-13-10023. Research on the synthesis of compounds 1–6, determination of their structures and the investigation of the sorption and luminescence properties was supported by the Russian Science Foundation, Grant No. 14-23-00013. The authors are grateful to Dr A. A. Ryadun for the luminescence studies. Publisher Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

PY - 2018

Y1 - 2018

N2 - Six isoreticular metal-organic frameworks (MOFs) based on zinc, cadmium and cobalt ions, 4,4′-stilbenedicarboxylic acid and the flexible ligands 1,4-bis(imidazol-1-yl)butane and 1,6-bis(imidazol-1-yl)hexane were prepared. The synergistic effect coming from the assembly of stilbenedicarboxylate and imidazolyl ligands led to multifunctional materials with excellent photoluminescence and good sorption capacity for carbon dioxide and iodine vapor.

AB - Six isoreticular metal-organic frameworks (MOFs) based on zinc, cadmium and cobalt ions, 4,4′-stilbenedicarboxylic acid and the flexible ligands 1,4-bis(imidazol-1-yl)butane and 1,6-bis(imidazol-1-yl)hexane were prepared. The synergistic effect coming from the assembly of stilbenedicarboxylate and imidazolyl ligands led to multifunctional materials with excellent photoluminescence and good sorption capacity for carbon dioxide and iodine vapor.

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Exploring the multifunctionality in metal-organic framework materials: How do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

Abstract

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