Experimental and Kinetic Modeling Studies of 3-Methylfuran Pyrolysis at Low and Atmospheric Pressures

Huaijiang Su; Jinglan Wang; Jiabiao Zou; Qiang Xu; Jiuzhong Yang; Zhanjun Cheng; Lixia Wei

doi:10.1021/acs.energyfuels.9b03594

Experimental and Kinetic Modeling Studies of 3-Methylfuran Pyrolysis at Low and Atmospheric Pressures

Huaijiang Su, Jinglan Wang, Jiabiao Zou, Qiang Xu, Jiuzhong Yang, Zhanjun Cheng^*, Lixia Wei

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Studies of 3-methylfuran (MF3) pyrolysis were carried out from 848 to 1373 K in a pyrolysis tube at 30 and 760 Torr using synchrotron vacuum ultraviolet photoionization mass spectrometry. Key products and intermediates were detected and measured, including methyl, propargyl, acetylene, ethylene, propyne/allene, vinylacetylene, propene, 1,3-butadiene, 2-butyne, ketene, etc. A pyrolysis model of MF3 was constructed and validated against the experimental data. The reaction pathways of MF3 decomposition, aromatics formation, and comparison between MF3 and 2-methylfuran pyrolysis were analyzed. The pyrolysis of MF3 was mainly controlled by the H-transfer reaction at 30 Torr. The H-transfer reaction and H-abstraction reaction dominated the consumption of MF3 at 760 Torr. MF3 had similar consumption pathways and slightly lower aromatics formation tendency than those of 2-methylfuran.

Original language	English (US)
Pages (from-to)	981-988
Number of pages	8
Journal	Energy and Fuels
Volume	34
Issue number	1
DOIs	https://doi.org/10.1021/acs.energyfuels.9b03594
State	Published - Jan 16 2020

Bibliographical note

Funding Information:
The authors thank the funding supports from the National Natural Science Foundation of China (no. 51776045), the Project Sponsored by the Scientific Research Foundation of Guangxi University (grant no. XGZ170074), and the National Key R&D Program of China (2016YFE0201800).

Publisher Copyright:
Copyright © 2019 American Chemical Society.

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology

Access to Document

10.1021/acs.energyfuels.9b03594

Cite this

@article{633b9cfd8cbb4fa9b4084e4d7ea9fb0e,

title = "Experimental and Kinetic Modeling Studies of 3-Methylfuran Pyrolysis at Low and Atmospheric Pressures",

abstract = "Studies of 3-methylfuran (MF3) pyrolysis were carried out from 848 to 1373 K in a pyrolysis tube at 30 and 760 Torr using synchrotron vacuum ultraviolet photoionization mass spectrometry. Key products and intermediates were detected and measured, including methyl, propargyl, acetylene, ethylene, propyne/allene, vinylacetylene, propene, 1,3-butadiene, 2-butyne, ketene, etc. A pyrolysis model of MF3 was constructed and validated against the experimental data. The reaction pathways of MF3 decomposition, aromatics formation, and comparison between MF3 and 2-methylfuran pyrolysis were analyzed. The pyrolysis of MF3 was mainly controlled by the H-transfer reaction at 30 Torr. The H-transfer reaction and H-abstraction reaction dominated the consumption of MF3 at 760 Torr. MF3 had similar consumption pathways and slightly lower aromatics formation tendency than those of 2-methylfuran.",

author = "Huaijiang Su and Jinglan Wang and Jiabiao Zou and Qiang Xu and Jiuzhong Yang and Zhanjun Cheng and Lixia Wei",

note = "Funding Information: The authors thank the funding supports from the National Natural Science Foundation of China (no. 51776045), the Project Sponsored by the Scientific Research Foundation of Guangxi University (grant no. XGZ170074), and the National Key R&D Program of China (2016YFE0201800). Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2020",

month = jan,

day = "16",

doi = "10.1021/acs.energyfuels.9b03594",

language = "English (US)",

volume = "34",

pages = "981--988",

journal = "Energy and Fuels",

issn = "0887-0624",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Experimental and Kinetic Modeling Studies of 3-Methylfuran Pyrolysis at Low and Atmospheric Pressures

AU - Su, Huaijiang

AU - Wang, Jinglan

AU - Zou, Jiabiao

AU - Xu, Qiang

AU - Yang, Jiuzhong

AU - Cheng, Zhanjun

AU - Wei, Lixia

N1 - Funding Information: The authors thank the funding supports from the National Natural Science Foundation of China (no. 51776045), the Project Sponsored by the Scientific Research Foundation of Guangxi University (grant no. XGZ170074), and the National Key R&D Program of China (2016YFE0201800). Publisher Copyright: Copyright © 2019 American Chemical Society.

PY - 2020/1/16

Y1 - 2020/1/16

N2 - Studies of 3-methylfuran (MF3) pyrolysis were carried out from 848 to 1373 K in a pyrolysis tube at 30 and 760 Torr using synchrotron vacuum ultraviolet photoionization mass spectrometry. Key products and intermediates were detected and measured, including methyl, propargyl, acetylene, ethylene, propyne/allene, vinylacetylene, propene, 1,3-butadiene, 2-butyne, ketene, etc. A pyrolysis model of MF3 was constructed and validated against the experimental data. The reaction pathways of MF3 decomposition, aromatics formation, and comparison between MF3 and 2-methylfuran pyrolysis were analyzed. The pyrolysis of MF3 was mainly controlled by the H-transfer reaction at 30 Torr. The H-transfer reaction and H-abstraction reaction dominated the consumption of MF3 at 760 Torr. MF3 had similar consumption pathways and slightly lower aromatics formation tendency than those of 2-methylfuran.

AB - Studies of 3-methylfuran (MF3) pyrolysis were carried out from 848 to 1373 K in a pyrolysis tube at 30 and 760 Torr using synchrotron vacuum ultraviolet photoionization mass spectrometry. Key products and intermediates were detected and measured, including methyl, propargyl, acetylene, ethylene, propyne/allene, vinylacetylene, propene, 1,3-butadiene, 2-butyne, ketene, etc. A pyrolysis model of MF3 was constructed and validated against the experimental data. The reaction pathways of MF3 decomposition, aromatics formation, and comparison between MF3 and 2-methylfuran pyrolysis were analyzed. The pyrolysis of MF3 was mainly controlled by the H-transfer reaction at 30 Torr. The H-transfer reaction and H-abstraction reaction dominated the consumption of MF3 at 760 Torr. MF3 had similar consumption pathways and slightly lower aromatics formation tendency than those of 2-methylfuran.

UR - http://www.scopus.com/inward/record.url?scp=85077693780&partnerID=8YFLogxK

U2 - 10.1021/acs.energyfuels.9b03594

DO - 10.1021/acs.energyfuels.9b03594

M3 - Article

AN - SCOPUS:85077693780

SN - 0887-0624

VL - 34

SP - 981

EP - 988

JO - Energy and Fuels

JF - Energy and Fuels

IS - 1

ER -

Experimental and Kinetic Modeling Studies of 3-Methylfuran Pyrolysis at Low and Atmospheric Pressures

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this