Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework

Aleksandr A. Sapianik; Konstantin A. Kovalenko; Denis G. Samsonenko; Marina O. Barsukova; Danil N. Dybtsev; Vladimir P. Fedin

doi:10.1039/d0cc03227a

Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework

Aleksandr A. Sapianik, Konstantin A. Kovalenko, Denis G. Samsonenko, Marina O. Barsukova, Danil N. Dybtsev, Vladimir P. Fedin

Advanced Membranes and Porous Materials Center

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Using a series of isoreticular MOFs with void connections of varying diameters, the selective separation of benzene and cyclohexane in both liquid and vapor phases is shown. The driving force of the highly efficient adsorption process is the formation of weak interactions between the adsorbed benzene molecules and the host framework.

Original language	English (US)
Pages (from-to)	8241-8244
Number of pages	4
Journal	CHEMICAL COMMUNICATIONS
Volume	56
Issue number	59
DOIs	https://doi.org/10.1039/d0cc03227a
State	Published - Jul 28 2020

Bibliographical note

Funding Information:
This study was supported by the Russian Science Foundation grant (no. 19-73-20087). Authors thank Dr P.V. Dorovatovskii and Dr V.A. Lazarenko for their assistance during the synchrotron XRD experiment.

Publisher Copyright:
© 2020 The Royal Society of Chemistry.

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc03227a

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title = "Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework",

abstract = "Using a series of isoreticular MOFs with void connections of varying diameters, the selective separation of benzene and cyclohexane in both liquid and vapor phases is shown. The driving force of the highly efficient adsorption process is the formation of weak interactions between the adsorbed benzene molecules and the host framework.",

author = "Sapianik, {Aleksandr A.} and Kovalenko, {Konstantin A.} and Samsonenko, {Denis G.} and Barsukova, {Marina O.} and Dybtsev, {Danil N.} and Fedin, {Vladimir P.}",

note = "Funding Information: This study was supported by the Russian Science Foundation grant (no. 19-73-20087). Authors thank Dr P.V. Dorovatovskii and Dr V.A. Lazarenko for their assistance during the synchrotron XRD experiment. Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

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T1 - Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework

AU - Sapianik, Aleksandr A.

AU - Kovalenko, Konstantin A.

AU - Samsonenko, Denis G.

AU - Barsukova, Marina O.

AU - Dybtsev, Danil N.

AU - Fedin, Vladimir P.

N1 - Funding Information: This study was supported by the Russian Science Foundation grant (no. 19-73-20087). Authors thank Dr P.V. Dorovatovskii and Dr V.A. Lazarenko for their assistance during the synchrotron XRD experiment. Publisher Copyright: © 2020 The Royal Society of Chemistry.

PY - 2020/7/28

Y1 - 2020/7/28

N2 - Using a series of isoreticular MOFs with void connections of varying diameters, the selective separation of benzene and cyclohexane in both liquid and vapor phases is shown. The driving force of the highly efficient adsorption process is the formation of weak interactions between the adsorbed benzene molecules and the host framework.

AB - Using a series of isoreticular MOFs with void connections of varying diameters, the selective separation of benzene and cyclohexane in both liquid and vapor phases is shown. The driving force of the highly efficient adsorption process is the formation of weak interactions between the adsorbed benzene molecules and the host framework.

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U2 - 10.1039/d0cc03227a

DO - 10.1039/d0cc03227a

M3 - Article

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ER -

Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework

Abstract

Bibliographical note

ASJC Scopus subject areas

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