Ethanol and water adsorption in methanol-derived ZIF-71

Ryan P. Lively, Michelle E. Dose, Joshua A. Thompson, Benjamin A. McCool, Ronald R. Chance, William J. Koros

Research output: Contribution to journalArticlepeer-review

99 Scopus citations

Abstract

A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.
Original languageEnglish (US)
Pages (from-to)8667
JournalChemical Communications
Volume47
Issue number30
DOIs
StatePublished - 2011
Externally publishedYes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-I1-011-21
Acknowledgements: J. A. Thompson and W. J. Koros gratefully acknowledge support for this work by award no. KUS-I1-011-21 made by King Abdullah University of Science and Technology (KAUST). This material is based upon work supported in part by the Department of Energy under Award Number DE-FOA-0000096.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

Fingerprint

Dive into the research topics of 'Ethanol and water adsorption in methanol-derived ZIF-71'. Together they form a unique fingerprint.

Cite this