Ethanol and water adsorption in methanol-derived ZIF-71

Ryan P. Lively; Michelle E. Dose; Joshua A. Thompson; Benjamin A. McCool; Ronald R. Chance; William J. Koros

doi:10.1039/c1cc12728d

Ethanol and water adsorption in methanol-derived ZIF-71

Ryan P. Lively, Michelle E. Dose, Joshua A. Thompson, Benjamin A. McCool, Ronald R. Chance, William J. Koros

Research output: Contribution to journal › Article › peer-review

103 Scopus citations

Abstract

A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.

Original language	English (US)
Pages (from-to)	8667
Journal	Chemical Communications
Volume	47
Issue number	30
DOIs	https://doi.org/10.1039/c1cc12728d
State	Published - 2011
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-I1-011-21
Acknowledgements: J. A. Thompson and W. J. Koros gratefully acknowledge support for this work by award no. KUS-I1-011-21 made by King Abdullah University of Science and Technology (KAUST). This material is based upon work supported in part by the Department of Energy under Award Number DE-FOA-0000096.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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title = "Ethanol and water adsorption in methanol-derived ZIF-71",

abstract = "A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. {\textcopyright} The Royal Society of Chemistry 2011.",

author = "Lively, {Ryan P.} and Dose, {Michelle E.} and Thompson, {Joshua A.} and McCool, {Benjamin A.} and Chance, {Ronald R.} and Koros, {William J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-I1-011-21 Acknowledgements: J. A. Thompson and W. J. Koros gratefully acknowledge support for this work by award no. KUS-I1-011-21 made by King Abdullah University of Science and Technology (KAUST). This material is based upon work supported in part by the Department of Energy under Award Number DE-FOA-0000096. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

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doi = "10.1039/c1cc12728d",

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AU - Lively, Ryan P.

AU - Dose, Michelle E.

AU - Thompson, Joshua A.

AU - McCool, Benjamin A.

AU - Chance, Ronald R.

AU - Koros, William J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-I1-011-21 Acknowledgements: J. A. Thompson and W. J. Koros gratefully acknowledge support for this work by award no. KUS-I1-011-21 made by King Abdullah University of Science and Technology (KAUST). This material is based upon work supported in part by the Department of Energy under Award Number DE-FOA-0000096. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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N2 - A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.

AB - A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.

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JO - Chemical Communications

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Ethanol and water adsorption in methanol-derived ZIF-71

Abstract

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