Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data

E.B. Starikov; B. Nordén

doi:10.1016/j.cplett.2012.04.028

Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data

E.B. Starikov, B. Nordén

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56 Scopus citations

Abstract

Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	118-120
Number of pages	3
Journal	Chemical Physics Letters
Volume	538
DOIs	https://doi.org/10.1016/j.cplett.2012.04.028
State	Published - Jun 2012
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: B.N. would like to acknowledge financial support from King Abdullah University of Science and Technology (KAUST).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1016/j.cplett.2012.04.028

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title = "Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data",

abstract = "Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. {\textcopyright} 2012 Elsevier B.V. All rights reserved.",

author = "E.B. Starikov and B. Nord{\'e}n",

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doi = "10.1016/j.cplett.2012.04.028",

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AU - Starikov, E.B.

AU - Nordén, B.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: B.N. would like to acknowledge financial support from King Abdullah University of Science and Technology (KAUST). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2012/6

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N2 - Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.

AB - Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors. © 2012 Elsevier B.V. All rights reserved.

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UR - https://linkinghub.elsevier.com/retrieve/pii/S000926141200509X

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DO - 10.1016/j.cplett.2012.04.028

M3 - Article

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VL - 538

SP - 118

EP - 120

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Entropy–enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data

Abstract

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