Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis

Maxim A. Nasalevich; Maarten G. Goesten; Tom J. Savenije; Freek Kapteijn; Jorge Gascon

doi:10.1039/c3cc46398b

Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis

Maxim A. Nasalevich, Maarten G. Goesten, Tom J. Savenije, Freek Kapteijn, Jorge Gascon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

243 Scopus citations

Abstract

NH₂-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL-125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the bottlenecks in MOF photochemistry are studied in detail.

Original language	English (US)
Pages (from-to)	10575-10577
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS
Volume	49
Issue number	90
DOIs	https://doi.org/10.1039/c3cc46398b
State	Published - Oct 17 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc46398b

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title = "Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis",

abstract = "NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL-125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the bottlenecks in MOF photochemistry are studied in detail.",

author = "Nasalevich, {Maxim A.} and Goesten, {Maarten G.} and Savenije, {Tom J.} and Freek Kapteijn and Jorge Gascon",

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AU - Goesten, Maarten G.

AU - Savenije, Tom J.

AU - Kapteijn, Freek

AU - Gascon, Jorge

PY - 2013/10/17

Y1 - 2013/10/17

N2 - NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL-125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the bottlenecks in MOF photochemistry are studied in detail.

AB - NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL-125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination. The consequences of functionalization and the bottlenecks in MOF photochemistry are studied in detail.

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DO - 10.1039/c3cc46398b

M3 - Article

AN - SCOPUS:84886877735

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JO - CHEMICAL COMMUNICATIONS

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ER -

Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis

Abstract

ASJC Scopus subject areas

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