Enhanced oxygen diffusion in low barium-containing La0.2175Pr0.2175Ba0.145Sr0.4Fe0.8Co0.2O3−δ intermediate temperature solid oxide fuel cell cathodes

Vicente B. Vert; José M. Serra; John A. Kilner; Mónica Burriel

doi:10.1016/j.jpowsour.2012.04.041

Enhanced oxygen diffusion in low barium-containing La0.2175Pr0.2175Ba0.145Sr0.4Fe0.8Co0.2O3−δ intermediate temperature solid oxide fuel cell cathodes

Vicente B. Vert, José M. Serra, John A. Kilner, Mónica Burriel

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Isotopic tracer diffusion studies have been performed on the perovskite composition La 0.2175Pr 0.2175Ba 0.145Sr 0.4Fe 0.8Co 0.2O 3-δ to obtain the diffusion and surface exchange coefficients for oxygen. This material has been identified as a highly active electrocatalytic cathode for intermediate temperature solid oxide fuel cells. The oxygen diffusion coefficients obtained in the 450-650 °C temperature range are higher than the ones measured for most of the cathode materials reported in the literature and they agree with those calculated from electrochemical impedance spectroscopy measurements performed on symmetrical cells. © 2012 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	270-274
Number of pages	5
Journal	Journal of Power Sources
Volume	213
DOIs	https://doi.org/10.1016/j.jpowsour.2012.04.041
State	Published - Sep 2012
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Funding from the Universitat Politecnica de Valencia (grants FPI-UPV-2007-06 and PAID-00-10) and Spanish Government (grant ENE2011-24761) is kindly acknowledged. The research leading to these results has received funding from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no : PIEF-GA-2009-252711 and from King Abdullah University of Science and Technology (KAUST) through a research grant. The authors would like to thank S. Jimenez for material and sample preparation and Dr. S. Fearn, R. Charter and S. Cook for their help with ToF-SIMS analysis.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1016/j.jpowsour.2012.04.041

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@article{9bd20241a7644672a1a27c007208c414,

title = "Enhanced oxygen diffusion in low barium-containing La0.2175Pr0.2175Ba0.145Sr0.4Fe0.8Co0.2O3−δ intermediate temperature solid oxide fuel cell cathodes",

abstract = "Isotopic tracer diffusion studies have been performed on the perovskite composition La 0.2175Pr 0.2175Ba 0.145Sr 0.4Fe 0.8Co 0.2O 3-δ to obtain the diffusion and surface exchange coefficients for oxygen. This material has been identified as a highly active electrocatalytic cathode for intermediate temperature solid oxide fuel cells. The oxygen diffusion coefficients obtained in the 450-650 °C temperature range are higher than the ones measured for most of the cathode materials reported in the literature and they agree with those calculated from electrochemical impedance spectroscopy measurements performed on symmetrical cells. {\textcopyright} 2012 Elsevier B.V. All rights reserved.",

author = "Vert, {Vicente B.} and Serra, {Jos{\'e} M.} and Kilner, {John A.} and M{\'o}nica Burriel",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Funding from the Universitat Politecnica de Valencia (grants FPI-UPV-2007-06 and PAID-00-10) and Spanish Government (grant ENE2011-24761) is kindly acknowledged. The research leading to these results has received funding from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no : PIEF-GA-2009-252711 and from King Abdullah University of Science and Technology (KAUST) through a research grant. The authors would like to thank S. Jimenez for material and sample preparation and Dr. S. Fearn, R. Charter and S. Cook for their help with ToF-SIMS analysis. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2012",

month = sep,

doi = "10.1016/j.jpowsour.2012.04.041",

language = "English (US)",

volume = "213",

pages = "270--274",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Enhanced oxygen diffusion in low barium-containing La0.2175Pr0.2175Ba0.145Sr0.4Fe0.8Co0.2O3−δ intermediate temperature solid oxide fuel cell cathodes

AU - Vert, Vicente B.

AU - Serra, José M.

AU - Kilner, John A.

AU - Burriel, Mónica

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Funding from the Universitat Politecnica de Valencia (grants FPI-UPV-2007-06 and PAID-00-10) and Spanish Government (grant ENE2011-24761) is kindly acknowledged. The research leading to these results has received funding from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no : PIEF-GA-2009-252711 and from King Abdullah University of Science and Technology (KAUST) through a research grant. The authors would like to thank S. Jimenez for material and sample preparation and Dr. S. Fearn, R. Charter and S. Cook for their help with ToF-SIMS analysis. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2012/9

Y1 - 2012/9

N2 - Isotopic tracer diffusion studies have been performed on the perovskite composition La 0.2175Pr 0.2175Ba 0.145Sr 0.4Fe 0.8Co 0.2O 3-δ to obtain the diffusion and surface exchange coefficients for oxygen. This material has been identified as a highly active electrocatalytic cathode for intermediate temperature solid oxide fuel cells. The oxygen diffusion coefficients obtained in the 450-650 °C temperature range are higher than the ones measured for most of the cathode materials reported in the literature and they agree with those calculated from electrochemical impedance spectroscopy measurements performed on symmetrical cells. © 2012 Elsevier B.V. All rights reserved.

AB - Isotopic tracer diffusion studies have been performed on the perovskite composition La 0.2175Pr 0.2175Ba 0.145Sr 0.4Fe 0.8Co 0.2O 3-δ to obtain the diffusion and surface exchange coefficients for oxygen. This material has been identified as a highly active electrocatalytic cathode for intermediate temperature solid oxide fuel cells. The oxygen diffusion coefficients obtained in the 450-650 °C temperature range are higher than the ones measured for most of the cathode materials reported in the literature and they agree with those calculated from electrochemical impedance spectroscopy measurements performed on symmetrical cells. © 2012 Elsevier B.V. All rights reserved.

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UR - https://linkinghub.elsevier.com/retrieve/pii/S0378775312007732

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DO - 10.1016/j.jpowsour.2012.04.041

M3 - Article

SN - 0378-7753

VL - 213

SP - 270

EP - 274

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Enhanced oxygen diffusion in low barium-containing La0.2175Pr0.2175Ba0.145Sr0.4Fe0.8Co0.2O3−δ intermediate temperature solid oxide fuel cell cathodes

Abstract

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