Enantiopure metal-organic framework thin films: Oriented SURMOF growth and enantioselective adsorption

Bo Liu; Osama Shekhah; Hasan K. Arslan; Jinxuan Liu; Christof Wöll; Roland A. Fischer

doi:10.1002/anie.201104240

Enantiopure metal-organic framework thin films: Oriented SURMOF growth and enantioselective adsorption

Bo Liu, Osama Shekhah, Hasan K. Arslan, Jinxuan Liu, Christof Wöll^*, Roland A. Fischer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

184 Scopus citations

Abstract

Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn ₂((+)cam) ₂(dabco)} _n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn ₂((±)cam) ₂(dabco)] pairs can be demonstrated (see picture).

Original language	English (US)
Pages (from-to)	807-810
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	3
DOIs	https://doi.org/10.1002/anie.201104240
State	Published - Jan 16 2012

Keywords

enantiopure metal-organic frameworks
enantioselective adsorption
quartz crystal microbalance
surface chemistry
thin films

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201104240

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title = "Enantiopure metal-organic framework thin films: Oriented SURMOF growth and enantioselective adsorption",

abstract = "Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn 2((+)cam) 2(dabco)} n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn 2((±)cam) 2(dabco)] pairs can be demonstrated (see picture).",

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T2 - Oriented SURMOF growth and enantioselective adsorption

AU - Liu, Bo

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AU - Arslan, Hasan K.

AU - Liu, Jinxuan

AU - Wöll, Christof

AU - Fischer, Roland A.

PY - 2012/1/16

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AB - Stuck on you: Preferred (110) and (001) orientation of enantiopure [{Zn 2((+)cam) 2(dabco)} n] ((+)cam=(1R,3S)-(+)- camphoric acid, dabco=1,4-diazabicyclo(2.2.2)octane) thin films can be controlled by carboxylate and pyridyl groups on self-assembled monolayers (SAMs). With a quartz crystal microbalance, the enantioselective adsorption of enantiomeric hexanediol pairs by enantiopure surface-attached metal-organic frameworks (SURMOF) [Zn 2((±)cam) 2(dabco)] pairs can be demonstrated (see picture).

KW - enantiopure metal-organic frameworks

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KW - surface chemistry

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Enantiopure metal-organic framework thin films: Oriented SURMOF growth and enantioselective adsorption

Abstract

Keywords

ASJC Scopus subject areas

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