Electronic Structure of Au25 Clusters: Between Discrete and Continuous

Khabiboulakh Katsiev, Nataliya Lozova, Lu Wang, Saikrishna Katla, Ruipeng Li, Wai Ning Mei, Sara Skrabalak, Challa Challa, Yaroslav Losovyj

Research output: Contribution to journalArticlepeer-review

5 Scopus citations


Here, an approach based on synchrotron resonant photoemission is emplyed to explore the transition between quantization and hybridization of the electronic structure in atomically precise ligand-stabilized nanoparticles. While the presence of ligands maintains quantization in Au25 clusters, their removal renders increased hybridization of the electronic states at the vicinity of the Fermi level. These observations are supported by DFT studies.
Original languageEnglish (US)
Pages (from-to)14711-14715
Number of pages5
Issue number31
StatePublished - 2016

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