Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

Noëlle Baute; Victor M. Geskin; Roberto Lazzaroni; Jean-Luc Bredas; Xavier Arys; Alain M. Jonas; Roger Legras; Claude Poleunis; Patrick Bertrand; Robert Jér̂me; Christine Jérôme

Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

Noëlle Baute, Victor M. Geskin, Roberto Lazzaroni, Jean-Luc Bredas, Xavier Arys, Alain M. Jonas, Roger Legras, Claude Poleunis, Patrick Bertrand, Robert Jér̂me, Christine Jérôme^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Adherent thin polymer films have been prepared by sequential electro-deposition of ethyl acrylate (EA) and acrylonitrile (AN) onto nickel. Their composition has been studied by IR spectroscopy and time of flight - secondary ion mass spectrometry. Morphology and thickness have been analyzed by atomic force microscopy and ellipsometry, respectively, and compared to single component films of PEA and PAN. No microphase separation was detected in the mixed PEA/PAN films. These show a granular morphology comparable to that of PAN films. The grains contain the two constitutive polymers, as confirmed by the selective thermal degradation of PEA.

Original language	English (US)
Journal	E-Polymers
State	Published - Oct 7 2004

ASJC Scopus subject areas

General Chemical Engineering
Physical and Theoretical Chemistry
Polymers and Plastics

Cite this

@article{fee991415685420ea3e39b1b4128f2d7,

title = "Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel",

abstract = "Adherent thin polymer films have been prepared by sequential electro-deposition of ethyl acrylate (EA) and acrylonitrile (AN) onto nickel. Their composition has been studied by IR spectroscopy and time of flight - secondary ion mass spectrometry. Morphology and thickness have been analyzed by atomic force microscopy and ellipsometry, respectively, and compared to single component films of PEA and PAN. No microphase separation was detected in the mixed PEA/PAN films. These show a granular morphology comparable to that of PAN films. The grains contain the two constitutive polymers, as confirmed by the selective thermal degradation of PEA.",

author = "No{\"e}lle Baute and Geskin, {Victor M.} and Roberto Lazzaroni and Jean-Luc Bredas and Xavier Arys and Jonas, {Alain M.} and Roger Legras and Claude Poleunis and Patrick Bertrand and Robert J{\'e}{\^r}me and Christine J{\'e}r{\^o}me",

year = "2004",

month = oct,

day = "7",

language = "English (US)",

journal = "E-Polymers",

issn = "1618-7229",

publisher = "Walter de Gruyter GmbH",

}

TY - JOUR

T1 - Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

AU - Baute, Noëlle

AU - Geskin, Victor M.

AU - Lazzaroni, Roberto

AU - Bredas, Jean-Luc

AU - Arys, Xavier

AU - Jonas, Alain M.

AU - Legras, Roger

AU - Poleunis, Claude

AU - Bertrand, Patrick

AU - Jér̂me, Robert

AU - Jérôme, Christine

PY - 2004/10/7

Y1 - 2004/10/7

N2 - Adherent thin polymer films have been prepared by sequential electro-deposition of ethyl acrylate (EA) and acrylonitrile (AN) onto nickel. Their composition has been studied by IR spectroscopy and time of flight - secondary ion mass spectrometry. Morphology and thickness have been analyzed by atomic force microscopy and ellipsometry, respectively, and compared to single component films of PEA and PAN. No microphase separation was detected in the mixed PEA/PAN films. These show a granular morphology comparable to that of PAN films. The grains contain the two constitutive polymers, as confirmed by the selective thermal degradation of PEA.

AB - Adherent thin polymer films have been prepared by sequential electro-deposition of ethyl acrylate (EA) and acrylonitrile (AN) onto nickel. Their composition has been studied by IR spectroscopy and time of flight - secondary ion mass spectrometry. Morphology and thickness have been analyzed by atomic force microscopy and ellipsometry, respectively, and compared to single component films of PEA and PAN. No microphase separation was detected in the mixed PEA/PAN films. These show a granular morphology comparable to that of PAN films. The grains contain the two constitutive polymers, as confirmed by the selective thermal degradation of PEA.

UR - http://www.scopus.com/inward/record.url?scp=18544367801&partnerID=8YFLogxK

M3 - Article

SN - 1618-7229

JO - E-Polymers

JF - E-Polymers

ER -

Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this