Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

Chunjing Lu; Teng Ben; Shixian Xu; Shilun Qiu

doi:10.1002/ange.201402950

Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

Chunjing Lu, Teng Ben, Shixian Xu, Shilun Qiu

Research output: Contribution to journal › Article › peer-review

130 Scopus citations

Abstract

A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.

Original language	English (US)
Pages (from-to)	6572-6576
Number of pages	5
Journal	Angewandte Chemie
Volume	126
Issue number	25
DOIs	https://doi.org/10.1002/ange.201402950
State	Published - May 22 2014
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009), and the Ministry of Education, Science and Technology Development Center Project (20120061130012).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1002/ange.201402950

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title = "Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film",

abstract = "A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.",

author = "Chunjing Lu and Teng Ben and Shixian Xu and Shilun Qiu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009), and the Ministry of Education, Science and Technology Development Center Project (20120061130012). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

month = may,

day = "22",

doi = "10.1002/ange.201402950",

language = "English (US)",

volume = "126",

pages = "6572--6576",

journal = "Angewandte Chemie",

issn = "0044-8249",

publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

AU - Lu, Chunjing

AU - Ben, Teng

AU - Xu, Shixian

AU - Qiu, Shilun

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009), and the Ministry of Education, Science and Technology Development Center Project (20120061130012). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014/5/22

Y1 - 2014/5/22

N2 - A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.

AB - A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.

UR - http://hdl.handle.net/10754/598141

UR - http://doi.wiley.com/10.1002/ange.201402950

U2 - 10.1002/ange.201402950

DO - 10.1002/ange.201402950

M3 - Article

SN - 0044-8249

VL - 126

SP - 6572

EP - 6576

JO - Angewandte Chemie

JF - Angewandte Chemie

IS - 25

ER -

Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

Abstract

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