Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film

Chunjing Lu, Teng Ben, Shixian Xu, Shilun Qiu

Research output: Contribution to journalArticlepeer-review

125 Scopus citations

Abstract

A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
Original languageEnglish (US)
Pages (from-to)6572-6576
Number of pages5
JournalAngewandte Chemie
Volume126
Issue number25
DOIs
StatePublished - May 22 2014
Externally publishedYes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009), and the Ministry of Education, Science and Technology Development Center Project (20120061130012).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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