Electrochemical characterization of LiCoO2 as rechargeable electrode in aqueous LiNO3 electrolyte

Riccardo Ruffo; Fabio La Mantia; Colin Wessells; Robert A. Huggins; Yi Cui

doi:10.1016/j.ssi.2010.05.043

Electrochemical characterization of LiCoO2 as rechargeable electrode in aqueous LiNO3 electrolyte

Riccardo Ruffo, Fabio La Mantia, Colin Wessells, Robert A. Huggins, Yi Cui

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

The development of lithium ion aqueous batteries is getting renewed interest due to their safety and low cost. We have demonstrated that the layer-structure LiCoO2 phase, the most commonly used electrode material in organic systems, can be successful delithiated and lithiated again in a water-based electrolyte at currents up to 2.70 A/g. The capacity is about 100 mAh/g at 0.135 A/g and can be tuned by cycling the electrode in different potential ranges. In fact, increasing the high cut-off voltage leads to higher specific capacity (up to 135 mAh/g) but the Coulomb efficiency is reduced (from 99.9% to 98.5%). The very good electrode kinetic is probably due to the high conductivity of the electrolyte solution (0.17 Scm- 1 at 25 °C) but this behavior is affected by the electrode load. © 2010 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	289-292
Number of pages	4
Journal	Solid State Ionics
Volume	192
Issue number	1
DOIs	https://doi.org/10.1016/j.ssi.2010.05.043
State	Published - Jun 2011
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-11-001-12
Acknowledgements: This work was supported by the King Abdullah University of Science and Technology (KAUST) under the award No. KUS-11-001-12, as well as GCEP at Stanford University.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

Access to Document

10.1016/j.ssi.2010.05.043

Cite this

@article{1f9ca371a6bd446c880246ab6faa55c3,

title = "Electrochemical characterization of LiCoO2 as rechargeable electrode in aqueous LiNO3 electrolyte",

abstract = "The development of lithium ion aqueous batteries is getting renewed interest due to their safety and low cost. We have demonstrated that the layer-structure LiCoO2 phase, the most commonly used electrode material in organic systems, can be successful delithiated and lithiated again in a water-based electrolyte at currents up to 2.70 A/g. The capacity is about 100 mAh/g at 0.135 A/g and can be tuned by cycling the electrode in different potential ranges. In fact, increasing the high cut-off voltage leads to higher specific capacity (up to 135 mAh/g) but the Coulomb efficiency is reduced (from 99.9% to 98.5%). The very good electrode kinetic is probably due to the high conductivity of the electrolyte solution (0.17 Scm- 1 at 25 °C) but this behavior is affected by the electrode load. {\textcopyright} 2010 Elsevier B.V. All rights reserved.",

author = "Riccardo Ruffo and {La Mantia}, Fabio and Colin Wessells and Huggins, {Robert A.} and Yi Cui",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-11-001-12 Acknowledgements: This work was supported by the King Abdullah University of Science and Technology (KAUST) under the award No. KUS-11-001-12, as well as GCEP at Stanford University. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2011",

month = jun,

doi = "10.1016/j.ssi.2010.05.043",

language = "English (US)",

volume = "192",

pages = "289--292",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Electrochemical characterization of LiCoO2 as rechargeable electrode in aqueous LiNO3 electrolyte

AU - Ruffo, Riccardo

AU - La Mantia, Fabio

AU - Wessells, Colin

AU - Huggins, Robert A.

AU - Cui, Yi

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-11-001-12 Acknowledgements: This work was supported by the King Abdullah University of Science and Technology (KAUST) under the award No. KUS-11-001-12, as well as GCEP at Stanford University. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2011/6

Y1 - 2011/6

N2 - The development of lithium ion aqueous batteries is getting renewed interest due to their safety and low cost. We have demonstrated that the layer-structure LiCoO2 phase, the most commonly used electrode material in organic systems, can be successful delithiated and lithiated again in a water-based electrolyte at currents up to 2.70 A/g. The capacity is about 100 mAh/g at 0.135 A/g and can be tuned by cycling the electrode in different potential ranges. In fact, increasing the high cut-off voltage leads to higher specific capacity (up to 135 mAh/g) but the Coulomb efficiency is reduced (from 99.9% to 98.5%). The very good electrode kinetic is probably due to the high conductivity of the electrolyte solution (0.17 Scm- 1 at 25 °C) but this behavior is affected by the electrode load. © 2010 Elsevier B.V. All rights reserved.

AB - The development of lithium ion aqueous batteries is getting renewed interest due to their safety and low cost. We have demonstrated that the layer-structure LiCoO2 phase, the most commonly used electrode material in organic systems, can be successful delithiated and lithiated again in a water-based electrolyte at currents up to 2.70 A/g. The capacity is about 100 mAh/g at 0.135 A/g and can be tuned by cycling the electrode in different potential ranges. In fact, increasing the high cut-off voltage leads to higher specific capacity (up to 135 mAh/g) but the Coulomb efficiency is reduced (from 99.9% to 98.5%). The very good electrode kinetic is probably due to the high conductivity of the electrolyte solution (0.17 Scm- 1 at 25 °C) but this behavior is affected by the electrode load. © 2010 Elsevier B.V. All rights reserved.

UR - http://hdl.handle.net/10754/598135

UR - https://linkinghub.elsevier.com/retrieve/pii/S0167273810002870

UR - http://www.scopus.com/inward/record.url?scp=79958824162&partnerID=8YFLogxK

U2 - 10.1016/j.ssi.2010.05.043

DO - 10.1016/j.ssi.2010.05.043

M3 - Article

SN - 0167-2738

VL - 192

SP - 289

EP - 292

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1

ER -

Electrochemical characterization of LiCoO2 as rechargeable electrode in aqueous LiNO3 electrolyte

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this