Efficient Splitting of Trans-/Cis-Olefins Using an Anion-Pillared Ultramicroporous Metal–Organic Framework with Guest-Adaptive Pore Channels

Zhaoqiang Zhang, Xili Cui, Xiaoming Jiang, Qi Ding, Jiyu Cui, Yuanbin Zhang, Youssef Belmabkhout, Karim Adil, Mohamed Eddaoudi, Huabin Xing

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Trans-/cis-olefin isomers play a vital role in the petrochemical industry. The paucity of energy-efficient technologies for their splitting is mainly due to the similarities of their physicochemical properties. Herein, two new tailor-made anion-pillared ultramicroporous metal–organic frameworks (MOFs), ZU-36-Ni and ZU-36-Fe (GeFSIX-3-Ni and GeFSIX-3-Fe) are reported for the first time for the efficient trans-/cis-2-butene (trans-/cis-C4H8) mixture splitting by enhanced molecular exclusion. Notably, ZU-36-Ni unexpectedly exhibited smart guest-adaptive pore channels for trapping trans-C4H8 with a remarkable adsorption capacity (2.45 mmol∙g−1) while effectively rejecting cis-C4H8 with a high purity of 99.99%. The dispersion-corrected density functional theory (DFT-D) calculation suggested that the guest-adaptive behavior of ZU-36-Ni in response to trans-C4H8 is derived from the organic linker rotation and the optimal pore dimensions, which not only improve the favorable adsorption/diffusion of trans-C4H8 with optimal host–guest interactions, but also enhance the size-exclusion of cis-C4H8. This work opens a new avenue for pore engineering in advanced smart or adaptive porous materials for specific applications involving guest molecular recognition.
Original languageEnglish (US)
JournalEngineering
DOIs
StatePublished - Dec 8 2021

Bibliographical note

KAUST Repository Item: Exported on 2022-04-21
Acknowledgements: Supported by the Zhejiang Provincial Natural Science Foundation of China (LZ18B060001), and the National Natural Science Foundation of China (21725603, 21476192, and U1862110)

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