Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides

Ibrahim Dursun; Yangzi Zheng; Tianle Guo; Michele de Bastiani; Bekir Turedi; Lutfan Sinatra; Mohammed Haque; Bin Sun; Ayan A. Zhumekenov; Makhsud I. Saidaminov; F. Pelayo Garcia de Arquer; Edward H. Sargent; Tao Wu; Yuri N Gartstein; Osman Bakr; Omar F. Mohammed; Anton V. Malko

doi:10.1021/acsenergylett.8b00758

Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides

Ibrahim Dursun, Yangzi Zheng, Tianle Guo, Michele de Bastiani, Bekir Turedi, Lutfan Sinatra, Mohammed Haque, Bin Sun, Ayan A. Zhumekenov, Makhsud I. Saidaminov, F. Pelayo Garcia de Arquer, Edward H. Sargent, Tao Wu, Yuri N Gartstein, Osman Bakr, Omar F. Mohammed, Anton V. Malko

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71 Scopus citations

Abstract

Cesium lead halide perovskite materials have attracted considerable attention for potential applications in lasers, light emitting diodes and photodetectors. Here, we provide the experimental and theoretical evidence for photon recycling in CsPbBr3 perovskite microwires. Using two-photon excitation, we recorded photoluminescence (PL) lifetimes and emission spectra as a function of the lateral distance between PL excitation and collection positions along the microwire, with separations exceeding 100 µm. At longer separations, the PL spectrum develops a red-shifted emission peak accompanied by an appearance of well-resolved rise times in the PL kinetics. We developed quantitative modeling that accounts for bimolecular recombination and photon recycling within the microwire waveguide and is sufficient to account for the observed decay modifications. It relies on a high radiative efficiency in CsPbBr3 perovskite microwires and provides crucial information about the potential impact of photon recycling and waveguide trapping on optoelectronic properties of cesium lead halide perovskite materials.

Original language	English (US)
Pages (from-to)	1492-1498
Number of pages	7
Journal	ACS Energy Letters
Volume	3
Issue number	7
DOIs	https://doi.org/10.1021/acsenergylett.8b00758
State	Published - May 25 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: KAUST group (ID, MDB, BT, LS, AAZ, OFM and OMB) gratefully acknowledge funding support from KAUST, Technology Innovation Center for Solid-State Lighting at KAUST. The work of UT Dallas group (YZ, TG, YNG and AVM) was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award No. DE-SC0010697. AVM gratefully acknowledges travel support from CRDF Global at early stages of the work. MIS acknowledges the Government of Canada’s Banting Postdoctoral Fellowship Program for financial support.

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10.1021/acsenergylett.8b00758

https://repository.kaust.edu.sa/bitstream/10754/627971/1/acsenergylett.8b00758.pdf

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Dursun, I., Zheng, Y., Guo, T., de Bastiani, M., Turedi, B., Sinatra, L., Haque, M., Sun, B., Zhumekenov, A. A., Saidaminov, M. I., Garcia de Arquer, F. P., Sargent, E. H., Wu, T., Gartstein, Y. N., Bakr, O., Mohammed, O. F., & Malko, A. V. (2018). Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides. ACS Energy Letters, 3(7), 1492-1498. https://doi.org/10.1021/acsenergylett.8b00758

@article{9d8d0dd4ac73495e8c02cd48bd2941a4,

title = "Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides",

abstract = "Cesium lead halide perovskite materials have attracted considerable attention for potential applications in lasers, light emitting diodes and photodetectors. Here, we provide the experimental and theoretical evidence for photon recycling in CsPbBr3 perovskite microwires. Using two-photon excitation, we recorded photoluminescence (PL) lifetimes and emission spectra as a function of the lateral distance between PL excitation and collection positions along the microwire, with separations exceeding 100 µm. At longer separations, the PL spectrum develops a red-shifted emission peak accompanied by an appearance of well-resolved rise times in the PL kinetics. We developed quantitative modeling that accounts for bimolecular recombination and photon recycling within the microwire waveguide and is sufficient to account for the observed decay modifications. It relies on a high radiative efficiency in CsPbBr3 perovskite microwires and provides crucial information about the potential impact of photon recycling and waveguide trapping on optoelectronic properties of cesium lead halide perovskite materials.",

author = "Ibrahim Dursun and Yangzi Zheng and Tianle Guo and {de Bastiani}, Michele and Bekir Turedi and Lutfan Sinatra and Mohammed Haque and Bin Sun and Zhumekenov, {Ayan A.} and Saidaminov, {Makhsud I.} and {Garcia de Arquer}, {F. Pelayo} and Sargent, {Edward H.} and Tao Wu and Gartstein, {Yuri N} and Osman Bakr and Mohammed, {Omar F.} and Malko, {Anton V.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: KAUST group (ID, MDB, BT, LS, AAZ, OFM and OMB) gratefully acknowledge funding support from KAUST, Technology Innovation Center for Solid-State Lighting at KAUST. The work of UT Dallas group (YZ, TG, YNG and AVM) was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award No. DE-SC0010697. AVM gratefully acknowledges travel support from CRDF Global at early stages of the work. MIS acknowledges the Government of Canada{\textquoteright}s Banting Postdoctoral Fellowship Program for financial support.",

year = "2018",

month = may,

day = "25",

doi = "10.1021/acsenergylett.8b00758",

language = "English (US)",

volume = "3",

pages = "1492--1498",

journal = "ACS Energy Letters",

issn = "2380-8195",

publisher = "American Chemical Society",

number = "7",

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Dursun, I, Zheng, Y, Guo, T, de Bastiani, M, Turedi, B, Sinatra, L, Haque, M, Sun, B, Zhumekenov, AA, Saidaminov, MI, Garcia de Arquer, FP, Sargent, EH, Wu, T, Gartstein, YN, Bakr, O , Mohammed, OF & Malko, AV 2018, 'Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides', ACS Energy Letters, vol. 3, no. 7, pp. 1492-1498. https://doi.org/10.1021/acsenergylett.8b00758

TY - JOUR

T1 - Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides

AU - Dursun, Ibrahim

AU - Zheng, Yangzi

AU - Guo, Tianle

AU - de Bastiani, Michele

AU - Turedi, Bekir

AU - Sinatra, Lutfan

AU - Haque, Mohammed

AU - Sun, Bin

AU - Zhumekenov, Ayan A.

AU - Saidaminov, Makhsud I.

AU - Garcia de Arquer, F. Pelayo

AU - Sargent, Edward H.

AU - Wu, Tao

AU - Gartstein, Yuri N

AU - Bakr, Osman

AU - Mohammed, Omar F.

AU - Malko, Anton V.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: KAUST group (ID, MDB, BT, LS, AAZ, OFM and OMB) gratefully acknowledge funding support from KAUST, Technology Innovation Center for Solid-State Lighting at KAUST. The work of UT Dallas group (YZ, TG, YNG and AVM) was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award No. DE-SC0010697. AVM gratefully acknowledges travel support from CRDF Global at early stages of the work. MIS acknowledges the Government of Canada’s Banting Postdoctoral Fellowship Program for financial support.

PY - 2018/5/25

Y1 - 2018/5/25

N2 - Cesium lead halide perovskite materials have attracted considerable attention for potential applications in lasers, light emitting diodes and photodetectors. Here, we provide the experimental and theoretical evidence for photon recycling in CsPbBr3 perovskite microwires. Using two-photon excitation, we recorded photoluminescence (PL) lifetimes and emission spectra as a function of the lateral distance between PL excitation and collection positions along the microwire, with separations exceeding 100 µm. At longer separations, the PL spectrum develops a red-shifted emission peak accompanied by an appearance of well-resolved rise times in the PL kinetics. We developed quantitative modeling that accounts for bimolecular recombination and photon recycling within the microwire waveguide and is sufficient to account for the observed decay modifications. It relies on a high radiative efficiency in CsPbBr3 perovskite microwires and provides crucial information about the potential impact of photon recycling and waveguide trapping on optoelectronic properties of cesium lead halide perovskite materials.

AB - Cesium lead halide perovskite materials have attracted considerable attention for potential applications in lasers, light emitting diodes and photodetectors. Here, we provide the experimental and theoretical evidence for photon recycling in CsPbBr3 perovskite microwires. Using two-photon excitation, we recorded photoluminescence (PL) lifetimes and emission spectra as a function of the lateral distance between PL excitation and collection positions along the microwire, with separations exceeding 100 µm. At longer separations, the PL spectrum develops a red-shifted emission peak accompanied by an appearance of well-resolved rise times in the PL kinetics. We developed quantitative modeling that accounts for bimolecular recombination and photon recycling within the microwire waveguide and is sufficient to account for the observed decay modifications. It relies on a high radiative efficiency in CsPbBr3 perovskite microwires and provides crucial information about the potential impact of photon recycling and waveguide trapping on optoelectronic properties of cesium lead halide perovskite materials.

UR - http://hdl.handle.net/10754/627971

UR - https://pubs.acs.org/doi/10.1021/acsenergylett.8b00758

UR - http://www.scopus.com/inward/record.url?scp=85047736507&partnerID=8YFLogxK

U2 - 10.1021/acsenergylett.8b00758

DO - 10.1021/acsenergylett.8b00758

M3 - Article

SN - 2380-8195

VL - 3

SP - 1492

EP - 1498

JO - ACS Energy Letters

JF - ACS Energy Letters

IS - 7

ER -

Efficient Photon Recycling and Radiation Trapping in Cesium Lead Halide Perovskite Waveguides

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