Efficient Near-Infrared Electroluminescence from Lanthanide-Doped Perovskite Quantum Cutters

Yan-Jun Yu; Chen Zou; Wan-Shan Shen; Xiaopeng Zheng; Qi-Sheng Tian; You-Jun Yu; Chun-Hao Chen; Baodan Zhao; Zhao-Kui Wang; Dawei Di; Osman Bakr; Liang-Sheng Liao

doi:10.1002/anie.202302005

Efficient Near-Infrared Electroluminescence from Lanthanide-Doped Perovskite Quantum Cutters

Yan-Jun Yu, Chen Zou, Wan-Shan Shen, Xiaopeng Zheng, Qi-Sheng Tian, You-Jun Yu, Chun-Hao Chen, Baodan Zhao, Zhao-Kui Wang, Dawei Di, Osman Bakr, Liang-Sheng Liao

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Perovskite nanocrystals (PeNCs) deliver size and composition-tunable luminescence of high efficiency and color purity in the visible. However, attaining efficient electroluminescence (EL) in the near-infrared (NIR) region from PeNCs is challenging, limiting their potential applications. Here we demonstrate a highly efficient NIR light emitting diode (LED) by doping ytterbium ions into the PeNCs host (Yb3+:PeNCs), extending the EL wavelengths toward 1000 nm, which is achieved through a direct sensitization of Yb3+ ions by the PeNC host. Efficient quantum cutting processes enable high photoluminescence quantum yields (PLQYs) of up to 126% from the Yb3+:PeNCs. Through halide-composition engineering and surface passivation strategy to improve both PLQY and charge transport balance, we demonstrate an efficient NIR LED with a peak EQE of 7.7% at a central wavelength of 990 nm, representing the most efficient perovskite-based LEDs with emission wavelengths beyond 850 nm.

Original language	English (US)
Journal	Angewandte Chemie (International ed. in English)
DOIs	https://doi.org/10.1002/anie.202302005
State	Published - Mar 25 2023

Bibliographical note

KAUST Repository Item: Exported on 2023-03-28
Acknowledgements: This work was supported by the National Natural Science Foundation of China (NSFC) (62175171,61961160731, 61975180, 62005243),the National Key R&D Program of China (grant no.2018YFB2200401), the Natural Science Foundation of Zhejiang Province (LR21F050003),Kun-Peng Program of Zhejiang Province (D.D.), Suzhou Key Laboratory of Functional Nano & Soft Materials, Collaborative Innovation Center of Suzhou Nano Science & Technology, the 111 Project, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices. This project is also funded by the Collaborative Innovation Center of Suzhou Nano Science and Technology (CIC-Nano), China and King Abdullah University of Science and Technology (KAUST).

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.202302005

https://repository.kaust.edu.sa/bitstream/10754/690655/1/Angew%20Chem%20Int%20Ed%20-%202023%20-%20Yu%20-%20Efficient%20Near%e2%80%90Infrared%20Electroluminescence%20from%20Lanthanide%e2%80%90Doped%20Perovskite%20Quantum_removed.pdf

Cite this

@article{dfe13891b7b345dd8946d92f0dc6b7d0,

title = "Efficient Near-Infrared Electroluminescence from Lanthanide-Doped Perovskite Quantum Cutters",

abstract = "Perovskite nanocrystals (PeNCs) deliver size and composition-tunable luminescence of high efficiency and color purity in the visible. However, attaining efficient electroluminescence (EL) in the near-infrared (NIR) region from PeNCs is challenging, limiting their potential applications. Here we demonstrate a highly efficient NIR light emitting diode (LED) by doping ytterbium ions into the PeNCs host (Yb3+:PeNCs), extending the EL wavelengths toward 1000 nm, which is achieved through a direct sensitization of Yb3+ ions by the PeNC host. Efficient quantum cutting processes enable high photoluminescence quantum yields (PLQYs) of up to 126% from the Yb3+:PeNCs. Through halide-composition engineering and surface passivation strategy to improve both PLQY and charge transport balance, we demonstrate an efficient NIR LED with a peak EQE of 7.7% at a central wavelength of 990 nm, representing the most efficient perovskite-based LEDs with emission wavelengths beyond 850 nm.",

author = "Yan-Jun Yu and Chen Zou and Wan-Shan Shen and Xiaopeng Zheng and Qi-Sheng Tian and You-Jun Yu and Chun-Hao Chen and Baodan Zhao and Zhao-Kui Wang and Dawei Di and Osman Bakr and Liang-Sheng Liao",

note = "KAUST Repository Item: Exported on 2023-03-28 Acknowledgements: This work was supported by the National Natural Science Foundation of China (NSFC) (62175171,61961160731, 61975180, 62005243),the National Key R&D Program of China (grant no.2018YFB2200401), the Natural Science Foundation of Zhejiang Province (LR21F050003),Kun-Peng Program of Zhejiang Province (D.D.), Suzhou Key Laboratory of Functional Nano & Soft Materials, Collaborative Innovation Center of Suzhou Nano Science & Technology, the 111 Project, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices. This project is also funded by the Collaborative Innovation Center of Suzhou Nano Science and Technology (CIC-Nano), China and King Abdullah University of Science and Technology (KAUST).",

year = "2023",

month = mar,

day = "25",

doi = "10.1002/anie.202302005",

language = "English (US)",

journal = "Angewandte Chemie (International ed. in English)",

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AU - Yu, Yan-Jun

AU - Zou, Chen

AU - Shen, Wan-Shan

AU - Zheng, Xiaopeng

AU - Tian, Qi-Sheng

AU - Yu, You-Jun

AU - Chen, Chun-Hao

AU - Zhao, Baodan

AU - Wang, Zhao-Kui

AU - Di, Dawei

AU - Bakr, Osman

AU - Liao, Liang-Sheng

N1 - KAUST Repository Item: Exported on 2023-03-28 Acknowledgements: This work was supported by the National Natural Science Foundation of China (NSFC) (62175171,61961160731, 61975180, 62005243),the National Key R&D Program of China (grant no.2018YFB2200401), the Natural Science Foundation of Zhejiang Province (LR21F050003),Kun-Peng Program of Zhejiang Province (D.D.), Suzhou Key Laboratory of Functional Nano & Soft Materials, Collaborative Innovation Center of Suzhou Nano Science & Technology, the 111 Project, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices. This project is also funded by the Collaborative Innovation Center of Suzhou Nano Science and Technology (CIC-Nano), China and King Abdullah University of Science and Technology (KAUST).

PY - 2023/3/25

Y1 - 2023/3/25

N2 - Perovskite nanocrystals (PeNCs) deliver size and composition-tunable luminescence of high efficiency and color purity in the visible. However, attaining efficient electroluminescence (EL) in the near-infrared (NIR) region from PeNCs is challenging, limiting their potential applications. Here we demonstrate a highly efficient NIR light emitting diode (LED) by doping ytterbium ions into the PeNCs host (Yb3+:PeNCs), extending the EL wavelengths toward 1000 nm, which is achieved through a direct sensitization of Yb3+ ions by the PeNC host. Efficient quantum cutting processes enable high photoluminescence quantum yields (PLQYs) of up to 126% from the Yb3+:PeNCs. Through halide-composition engineering and surface passivation strategy to improve both PLQY and charge transport balance, we demonstrate an efficient NIR LED with a peak EQE of 7.7% at a central wavelength of 990 nm, representing the most efficient perovskite-based LEDs with emission wavelengths beyond 850 nm.

AB - Perovskite nanocrystals (PeNCs) deliver size and composition-tunable luminescence of high efficiency and color purity in the visible. However, attaining efficient electroluminescence (EL) in the near-infrared (NIR) region from PeNCs is challenging, limiting their potential applications. Here we demonstrate a highly efficient NIR light emitting diode (LED) by doping ytterbium ions into the PeNCs host (Yb3+:PeNCs), extending the EL wavelengths toward 1000 nm, which is achieved through a direct sensitization of Yb3+ ions by the PeNC host. Efficient quantum cutting processes enable high photoluminescence quantum yields (PLQYs) of up to 126% from the Yb3+:PeNCs. Through halide-composition engineering and surface passivation strategy to improve both PLQY and charge transport balance, we demonstrate an efficient NIR LED with a peak EQE of 7.7% at a central wavelength of 990 nm, representing the most efficient perovskite-based LEDs with emission wavelengths beyond 850 nm.

UR - http://hdl.handle.net/10754/690655

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DO - 10.1002/anie.202302005

M3 - Article

C2 - 36965042

SN - 1433-7851

JO - Angewandte Chemie (International ed. in English)

JF - Angewandte Chemie (International ed. in English)

ER -

Efficient Near-Infrared Electroluminescence from Lanthanide-Doped Perovskite Quantum Cutters

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