Effects of alkyl chain positioning on conjugated polymer microstructure and field-effect mobilities

Bob C. Schroeder; Christian B. Nielsen; Paul Westacott; Jeremy Smith; Stephan Rossbauer; Thomas D. Anthopoulos; Natalie Stingelin; Iain McCulloch

doi:10.1557/mrc.2015.49

Effects of alkyl chain positioning on conjugated polymer microstructure and field-effect mobilities

Bob C. Schroeder, Christian B. Nielsen, Paul Westacott, Jeremy Smith, Stephan Rossbauer, Thomas D. Anthopoulos, Natalie Stingelin, Iain McCulloch

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3 Scopus citations

Abstract

Solubilizing alkyl chains play a crucial role in the design of semiconducting polymers because they define the materials solubility and processability as well as both the crystallinity and solid-state microstructure. In this paper, we present a scarcely explored design approach by attaching the alkyl side chains on one side (cis-) or on both sides (trans-) of the conjugated backbone. We further investigate the effects of this structural modification on the solid-state properties of the polymers and on the charge-carrier mobilities in organic thin-film transistors. Copyright © Materials Research Society 2015

Original language	English (US)
Pages (from-to)	435-440
Number of pages	6
Journal	MRS Communications
Volume	5
Issue number	3
DOIs	https://doi.org/10.1557/mrc.2015.49
State	Published - Jul 2 2015

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title = "Effects of alkyl chain positioning on conjugated polymer microstructure and field-effect mobilities",

abstract = "Solubilizing alkyl chains play a crucial role in the design of semiconducting polymers because they define the materials solubility and processability as well as both the crystallinity and solid-state microstructure. In this paper, we present a scarcely explored design approach by attaching the alkyl side chains on one side (cis-) or on both sides (trans-) of the conjugated backbone. We further investigate the effects of this structural modification on the solid-state properties of the polymers and on the charge-carrier mobilities in organic thin-film transistors. Copyright {\textcopyright} Materials Research Society 2015",

author = "Schroeder, {Bob C.} and Nielsen, {Christian B.} and Paul Westacott and Jeremy Smith and Stephan Rossbauer and Anthopoulos, {Thomas D.} and Natalie Stingelin and Iain McCulloch",

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AU - Schroeder, Bob C.

AU - Nielsen, Christian B.

AU - Westacott, Paul

AU - Smith, Jeremy

AU - Rossbauer, Stephan

AU - Anthopoulos, Thomas D.

AU - Stingelin, Natalie

AU - McCulloch, Iain

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2015/7/2

Y1 - 2015/7/2

N2 - Solubilizing alkyl chains play a crucial role in the design of semiconducting polymers because they define the materials solubility and processability as well as both the crystallinity and solid-state microstructure. In this paper, we present a scarcely explored design approach by attaching the alkyl side chains on one side (cis-) or on both sides (trans-) of the conjugated backbone. We further investigate the effects of this structural modification on the solid-state properties of the polymers and on the charge-carrier mobilities in organic thin-film transistors. Copyright © Materials Research Society 2015

AB - Solubilizing alkyl chains play a crucial role in the design of semiconducting polymers because they define the materials solubility and processability as well as both the crystallinity and solid-state microstructure. In this paper, we present a scarcely explored design approach by attaching the alkyl side chains on one side (cis-) or on both sides (trans-) of the conjugated backbone. We further investigate the effects of this structural modification on the solid-state properties of the polymers and on the charge-carrier mobilities in organic thin-film transistors. Copyright © Materials Research Society 2015

UR - http://hdl.handle.net/10754/594205

UR - https://www.cambridge.org/core/product/identifier/S215968591500049X/type/journal_article

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DO - 10.1557/mrc.2015.49

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SP - 435

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JO - MRS Communications

JF - MRS Communications

IS - 3

ER -

Effects of alkyl chain positioning on conjugated polymer microstructure and field-effect mobilities

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