Abstract
The effective stimulated emission cross-section spectra of a para-phenylene-vinylene polymer and of two para-phenylene-ethynylene polymers are determined by a fluorescence amplification technique. For these luminescent polymers laser action has been achieved in solution. The effective stimulated emission cross-section spectra are found to be small compared to the stimulated emission cross-section spectra calculated from fluorescence quantum distribution and fluorescence lifetime measurements. The laser excitation of the polymer solutions seems to form lattice relaxed exciton conformations extending over a few monomer units which are thought to be responsible for upper-to-lower-state stimulated emission and lower-to-upper-state (excited-state) absorption.
Original language | English (US) |
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Title of host publication | Proceedings of SPIE - The International Society for Optical Engineering |
Publisher | SPIEBellingham, WA, United States |
State | Published - Dec 1 1998 |
Externally published | Yes |