Effect of Sm-doping on the hydrogen permeation of Ni-La2Ce2O7 mixed protonic-electronic conductor

Litao Yan, Wenping Sun, Lei Bi, Shumin Fang, Zetian Tao, Wei Liu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

59 Scopus citations

Abstract

The cermet consisting of electronic conductor Ni and proton conductor La2Ce2O7 (LDC) shows good chemical stability but poor hydrogen permeability. In order to improve the hydrogen permeability, novel Ni-La2-xSmxCe2O7 (x = 0, 0.025, 0.05, 0.075, 0.1 and 0.2) cermets were developed for hydrogen separation. The results show that Sm element doping of LDC can affect the rate of hydrogen permeation, with Ni-La1.95Sm0.05Ce2O7 possessing the highest hydrogen permeation fluxes.

Original languageEnglish (US)
Pages (from-to)4508-4511
Number of pages4
JournalInternational Journal of Hydrogen Energy
Volume35
Issue number10
DOIs
StatePublished - May 2010
Externally publishedYes

Bibliographical note

Funding Information:
We gratefully acknowledge the support of National High-tech R&D Program of China (no. 2007AA05Z157), Key Program of Chinese Academy of Sciences (no. KJCX1.YW07), and the CAS Special Grant for Postgraduate Research, Innovation and Practice.

Keywords

  • Cermet
  • Hydrogen separation
  • Proton conductor

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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