Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials

Youngjune Park; Camille Petit; Patrick Han; Ah-Hyung Alissa Park

doi:10.1039/c3ra46801a

Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials

Youngjune Park, Camille Petit, Patrick Han, Ah-Hyung Alissa Park

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39 Scopus citations

Abstract

Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. © The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	8723
Journal	RSC Advances
Volume	4
Issue number	17
DOIs	https://doi.org/10.1039/c3ra46801a
State	Published - 2014
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-C1-018-02
Acknowledgements: This publication was based on work supported by Award no. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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title = "Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials",

abstract = "Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. {\textcopyright} The Royal Society of Chemistry.",

author = "Youngjune Park and Camille Petit and Patrick Han and {Alissa Park}, Ah-Hyung",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-C1-018-02 Acknowledgements: This publication was based on work supported by Award no. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

doi = "10.1039/c3ra46801a",

language = "English (US)",

volume = "4",

pages = "8723",

journal = "RSC Advances",

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publisher = "ROYAL SOC CHEMISTRY",

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T1 - Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials

AU - Park, Youngjune

AU - Petit, Camille

AU - Han, Patrick

AU - Alissa Park, Ah-Hyung

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): KUS-C1-018-02 Acknowledgements: This publication was based on work supported by Award no. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014

Y1 - 2014

N2 - Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. © The Royal Society of Chemistry.

AB - Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. © The Royal Society of Chemistry.

UR - http://hdl.handle.net/10754/598050

UR - http://xlink.rsc.org/?DOI=c3ra46801a

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DO - 10.1039/c3ra46801a

M3 - Article

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VL - 4

SP - 8723

JO - RSC Advances

JF - RSC Advances

IS - 17

ER -

Effect of canopy structures and their steric interactions on CO2 sorption behavior of liquid-like nanoparticle organic hybrid materials

Abstract

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