Liquid-like NOHMs with different grafting densities of polymeric canopy were synthesized to evaluate their solvating properties as CO2 solvents. The in situ ATR FT-IR study of NOHMs with linear and branched canopies revealed distinct CO2 capture and corresponding swelling behaviors. These observations suggested that the entropic contribution for CO2 sorption in NOHMs can be tuned via the canopy design. © The Royal Society of Chemistry.
|Original language||English (US)|
|State||Published - 2014|
Bibliographical noteKAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): KUS-C1-018-02
Acknowledgements: This publication was based on work supported by Award no. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.