Dual catalysis: Combination of photocatalytic aerobic oxidation and metal catalyzed alkynylation reactions-C-C bond formation using visible light

Magnus Rueping; René M. Koenigs; Konstantin Poscharny; David C. Fabry; Daniele Leonori; Carlos Vila

doi:10.1002/chem.201200050

Dual catalysis: Combination of photocatalytic aerobic oxidation and metal catalyzed alkynylation reactions-C-C bond formation using visible light

Magnus Rueping^*, René M. Koenigs, Konstantin Poscharny, David C. Fabry, Daniele Leonori, Carlos Vila

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

222 Scopus citations

Abstract

Shedding new light on the right combination of catalysts: A new dual catalytic system for efficient C-H functionalization was developed. The appropriate choice of two metal catalysts allows the oxidative alkynylation of tertiary amines under mild and sustainable reaction conditions.

Original language	English (US)
Pages (from-to)	5170-5174
Number of pages	5
Journal	Chemistry - A European Journal
Volume	18
Issue number	17
DOIs	https://doi.org/10.1002/chem.201200050
State	Published - Apr 23 2012
Externally published	Yes

Keywords

C-C coupling
C-H activation
alkynylation
oxidation
photocatalysis

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201200050

Cite this

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abstract = "Shedding new light on the right combination of catalysts: A new dual catalytic system for efficient C-H functionalization was developed. The appropriate choice of two metal catalysts allows the oxidative alkynylation of tertiary amines under mild and sustainable reaction conditions.",

keywords = "C-C coupling, C-H activation, alkynylation, oxidation, photocatalysis",

author = "Magnus Rueping and Koenigs, {Ren{\'e} M.} and Konstantin Poscharny and Fabry, {David C.} and Daniele Leonori and Carlos Vila",

year = "2012",

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AU - Rueping, Magnus

AU - Koenigs, René M.

AU - Poscharny, Konstantin

AU - Fabry, David C.

AU - Leonori, Daniele

AU - Vila, Carlos

PY - 2012/4/23

Y1 - 2012/4/23

N2 - Shedding new light on the right combination of catalysts: A new dual catalytic system for efficient C-H functionalization was developed. The appropriate choice of two metal catalysts allows the oxidative alkynylation of tertiary amines under mild and sustainable reaction conditions.

AB - Shedding new light on the right combination of catalysts: A new dual catalytic system for efficient C-H functionalization was developed. The appropriate choice of two metal catalysts allows the oxidative alkynylation of tertiary amines under mild and sustainable reaction conditions.

KW - C-C coupling

KW - C-H activation

KW - alkynylation

KW - oxidation

KW - photocatalysis

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M3 - Article

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AN - SCOPUS:84859910319

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Dual catalysis: Combination of photocatalytic aerobic oxidation and metal catalyzed alkynylation reactions-C-C bond formation using visible light

Abstract

Keywords

ASJC Scopus subject areas

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