Dual catalysis: A combined enantioselective brønsted acid and metal-catalyzed reaction - Metal catalysis with chiral counterions

Magnus Rueping; Andrey P. Antonchick; Claus Brinkmann

doi:10.1002/anie.200702439

Dual catalysis: A combined enantioselective brønsted acid and metal-catalyzed reaction - Metal catalysis with chiral counterions

Magnus Rueping^*, Andrey P. Antonchick, Claus Brinkmann

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

299 Scopus citations

Abstract

(Chemical Equation Presented) Double take: The combination of enantioselective Brønsted acid catalyzed activation and metal-catalyzed alkynylation of α-imino esters under mild reaction conditions leads to amino acids in high yields and with excellent e.r. values (see scheme; PG = protecting group).

Original language	English (US)
Pages (from-to)	6903-6906
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	36
DOIs	https://doi.org/10.1002/anie.200702439
State	Published - 2007
Externally published	Yes

Keywords

Alkynes
Asymmetric catalysis
Binol phosphate
Silver

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.200702439

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title = "Dual catalysis: A combined enantioselective br{\o}nsted acid and metal-catalyzed reaction - Metal catalysis with chiral counterions",

abstract = "(Chemical Equation Presented) Double take: The combination of enantioselective Br{\o}nsted acid catalyzed activation and metal-catalyzed alkynylation of α-imino esters under mild reaction conditions leads to amino acids in high yields and with excellent e.r. values (see scheme; PG = protecting group).",

keywords = "Alkynes, Asymmetric catalysis, Binol phosphate, Silver",

author = "Magnus Rueping and Antonchick, {Andrey P.} and Claus Brinkmann",

year = "2007",

doi = "10.1002/anie.200702439",

language = "English (US)",

volume = "46",

pages = "6903--6906",

journal = "Angewandte Chemie - International Edition",

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publisher = "Wiley",

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T2 - A combined enantioselective brønsted acid and metal-catalyzed reaction - Metal catalysis with chiral counterions

AU - Rueping, Magnus

AU - Antonchick, Andrey P.

AU - Brinkmann, Claus

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) Double take: The combination of enantioselective Brønsted acid catalyzed activation and metal-catalyzed alkynylation of α-imino esters under mild reaction conditions leads to amino acids in high yields and with excellent e.r. values (see scheme; PG = protecting group).

AB - (Chemical Equation Presented) Double take: The combination of enantioselective Brønsted acid catalyzed activation and metal-catalyzed alkynylation of α-imino esters under mild reaction conditions leads to amino acids in high yields and with excellent e.r. values (see scheme; PG = protecting group).

KW - Alkynes

KW - Asymmetric catalysis

KW - Binol phosphate

KW - Silver

UR - http://www.scopus.com/inward/record.url?scp=34548725044&partnerID=8YFLogxK

U2 - 10.1002/anie.200702439

DO - 10.1002/anie.200702439

M3 - Article

C2 - 17694520

AN - SCOPUS:34548725044

SN - 1433-7851

VL - 46

SP - 6903

EP - 6906

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Dual catalysis: A combined enantioselective brønsted acid and metal-catalyzed reaction - Metal catalysis with chiral counterions

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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