Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction

Kuo-Wei Huang; Huaifeng Li; Theo Goncalves; Qianyi Zhao; Dirong Gong; Zhiping Lai; Zhi-Xiang Wang; Junrong Zheng

doi:10.1039/c8cc05948a

Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction

Kuo-Wei Huang, Huaifeng Li, Theo Goncalves, Qianyi Zhao, Dirong Gong, Zhiping Lai, Zhi-Xiang Wang, Junrong Zheng

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

A dearomatized PN3P*-nickel hydride complex has been prepared by oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selectvie methylation and formylation of amines with CO2 were demonstrated by such PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.

Original language	English (US)
Pages (from-to)	11395-11398
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	81
DOIs	https://doi.org/10.1039/c8cc05948a
State	Published - 2018

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10.1039/c8cc05948a

https://repository.kaust.edu.sa/bitstream/10754/628474/1/c8cc05948a.pdf

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title = "Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction",

abstract = "A dearomatized PN3P*-nickel hydride complex has been prepared by oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selectvie methylation and formylation of amines with CO2 were demonstrated by such PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.",

author = "Kuo-Wei Huang and Huaifeng Li and Theo Goncalves and Qianyi Zhao and Dirong Gong and Zhiping Lai and Zhi-Xiang Wang and Junrong Zheng",

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pages = "11395--11398",

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T1 - Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction

AU - Huang, Kuo-Wei

AU - Li, Huaifeng

AU - Goncalves, Theo

AU - Zhao, Qianyi

AU - Gong, Dirong

AU - Lai, Zhiping

AU - Wang, Zhi-Xiang

AU - Zheng, Junrong

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2018

Y1 - 2018

N2 - A dearomatized PN3P*-nickel hydride complex has been prepared by oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selectvie methylation and formylation of amines with CO2 were demonstrated by such PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.

AB - A dearomatized PN3P*-nickel hydride complex has been prepared by oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selectvie methylation and formylation of amines with CO2 were demonstrated by such PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.

UR - http://hdl.handle.net/10754/628474

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC05948A#!divAbstract

UR - http://www.scopus.com/inward/record.url?scp=85054700730&partnerID=8YFLogxK

U2 - 10.1039/c8cc05948a

DO - 10.1039/c8cc05948a

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C2 - 30175825

SN - 1359-7345

VL - 54

SP - 11395

EP - 11398

JO - Chemical Communications

JF - Chemical Communications

IS - 81

ER -

Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction

Abstract

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CCDC 1505721: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-(6-((di-t-butylphosphino)amino)pyridin-2(1H)-ylidene)phosphinous amidato)-(hydrido)-nickel

CCDC 1571043: Experimental Crystal Structure Determination : (P,P-dicyclopentyl-N-{6-[(dicyclopentylphosphino)amino]pyridin-2(1H)-ylidene}phosphinous amidato)-hydrido-nickel

CCDC 1530059: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butyl-phosphanylidene)amino]pyridin-2-yl}-N-methylphosphinous amide)-hydrido-nickel(ii)

Cite this

Diverse catalytic reactivity of a dearomatized PN3P*-nickel hydride pincer complex towards CO2 reduction

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1505721: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-(6-((di-t-butylphosphino)amino)pyridin-2(1H)-ylidene)phosphinous amidato)-(hydrido)-nickel

CCDC 1571043: Experimental Crystal Structure Determination : (P,P-dicyclopentyl-N-{6-[(dicyclopentylphosphino)amino]pyridin-2(1H)-ylidene}phosphinous amidato)-hydrido-nickel

CCDC 1530059: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butyl-phosphanylidene)amino]pyridin-2-yl}-N-methylphosphinous amide)-hydrido-nickel(ii)

Cite this