Divalent manganese linked tungsten-molybdenum polyoxometalates: Synthesis, structure, and magnetic characteristics

Xiutang Zhang; Jianmin Dou; Daqi Wang; Yuexing Zhang; Yang Zhou; Renjie Li; Shishen Yan; Zhonghai Ni; Jianzhuang Jiang

doi:10.1021/cg060723f

Divalent manganese linked tungsten-molybdenum polyoxometalates: Synthesis, structure, and magnetic characteristics

Xiutang Zhang, Jianmin Dou, Daqi Wang, Yuexing Zhang, Yang Zhou, Renjie Li, Shishen Yan, Zhonghai Ni^*, Jianzhuang Jiang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Three novel tungsten-molybdenum polyoxometalate compounds, namely H _2.5K₂[Mn_1.5W_5.65Mo _1.35O₂₄(H₂O)₄]Cl _1.5· 6H₂O (1), H₅K₂Na[Mn ₂(H₂O)₆(H₂W_9.52Mo _2.48O₄₂)]Cl₂·20H₂O (2), and Na₂[Mn₄(H₂O)₁₄(H₂W ₁₂O₄₂)]·16H₂O (3), were prepared and characterized by elemental analysis and IR spectroscopy. Single-crystal X-ray diffraction analyses reveal their three-dimensional network composed of a framework of M₇O₂₄^6- or H₂M ₁₂O₄₂^10- (M = W or W/Mo) linked via divalent manganese cations Mn(H₂O)_n²⁺ (n = 2-4), with the help of potassium for 1 and 2. Magnetic measurements reveal that all the three compounds 1-3 show paramagnetic properties with a magnetic moment about the single Mn²⁺ cation, indicating very weak antiferromagnetic coupling between the neighboring Mn²⁺ cations in these three-dimensional architectures.

Original language	English (US)
Pages (from-to)	1699-1705
Number of pages	7
Journal	Crystal Growth and Design
Volume	7
Issue number	9
DOIs	https://doi.org/10.1021/cg060723f
State	Published - Sep 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1021/cg060723f

Cite this

@article{cfdef1a2f05944efbf4d22dc88cf24cd,

title = "Divalent manganese linked tungsten-molybdenum polyoxometalates: Synthesis, structure, and magnetic characteristics",

abstract = "Three novel tungsten-molybdenum polyoxometalate compounds, namely H 2.5K2[Mn1.5W5.65Mo 1.35O24(H2O)4]Cl 1.5· 6H2O (1), H5K2Na[Mn 2(H2O)6(H2W9.52Mo 2.48O42)]Cl2·20H2O (2), and Na2[Mn4(H2O)14(H2W 12O42)]·16H2O (3), were prepared and characterized by elemental analysis and IR spectroscopy. Single-crystal X-ray diffraction analyses reveal their three-dimensional network composed of a framework of M7O246- or H2M 12O4210- (M = W or W/Mo) linked via divalent manganese cations Mn(H2O)n2+ (n = 2-4), with the help of potassium for 1 and 2. Magnetic measurements reveal that all the three compounds 1-3 show paramagnetic properties with a magnetic moment about the single Mn2+ cation, indicating very weak antiferromagnetic coupling between the neighboring Mn2+ cations in these three-dimensional architectures.",

author = "Xiutang Zhang and Jianmin Dou and Daqi Wang and Yuexing Zhang and Yang Zhou and Renjie Li and Shishen Yan and Zhonghai Ni and Jianzhuang Jiang",

year = "2007",

month = sep,

doi = "10.1021/cg060723f",

language = "English (US)",

volume = "7",

pages = "1699--1705",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Divalent manganese linked tungsten-molybdenum polyoxometalates

T2 - Synthesis, structure, and magnetic characteristics

AU - Zhang, Xiutang

AU - Dou, Jianmin

AU - Wang, Daqi

AU - Zhang, Yuexing

AU - Zhou, Yang

AU - Li, Renjie

AU - Yan, Shishen

AU - Ni, Zhonghai

AU - Jiang, Jianzhuang

PY - 2007/9

Y1 - 2007/9

N2 - Three novel tungsten-molybdenum polyoxometalate compounds, namely H 2.5K2[Mn1.5W5.65Mo 1.35O24(H2O)4]Cl 1.5· 6H2O (1), H5K2Na[Mn 2(H2O)6(H2W9.52Mo 2.48O42)]Cl2·20H2O (2), and Na2[Mn4(H2O)14(H2W 12O42)]·16H2O (3), were prepared and characterized by elemental analysis and IR spectroscopy. Single-crystal X-ray diffraction analyses reveal their three-dimensional network composed of a framework of M7O246- or H2M 12O4210- (M = W or W/Mo) linked via divalent manganese cations Mn(H2O)n2+ (n = 2-4), with the help of potassium for 1 and 2. Magnetic measurements reveal that all the three compounds 1-3 show paramagnetic properties with a magnetic moment about the single Mn2+ cation, indicating very weak antiferromagnetic coupling between the neighboring Mn2+ cations in these three-dimensional architectures.

AB - Three novel tungsten-molybdenum polyoxometalate compounds, namely H 2.5K2[Mn1.5W5.65Mo 1.35O24(H2O)4]Cl 1.5· 6H2O (1), H5K2Na[Mn 2(H2O)6(H2W9.52Mo 2.48O42)]Cl2·20H2O (2), and Na2[Mn4(H2O)14(H2W 12O42)]·16H2O (3), were prepared and characterized by elemental analysis and IR spectroscopy. Single-crystal X-ray diffraction analyses reveal their three-dimensional network composed of a framework of M7O246- or H2M 12O4210- (M = W or W/Mo) linked via divalent manganese cations Mn(H2O)n2+ (n = 2-4), with the help of potassium for 1 and 2. Magnetic measurements reveal that all the three compounds 1-3 show paramagnetic properties with a magnetic moment about the single Mn2+ cation, indicating very weak antiferromagnetic coupling between the neighboring Mn2+ cations in these three-dimensional architectures.

UR - http://www.scopus.com/inward/record.url?scp=34748885075&partnerID=8YFLogxK

U2 - 10.1021/cg060723f

DO - 10.1021/cg060723f

M3 - Article

AN - SCOPUS:34748885075

SN - 1528-7483

VL - 7

SP - 1699

EP - 1705

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 9

ER -

Divalent manganese linked tungsten-molybdenum polyoxometalates: Synthesis, structure, and magnetic characteristics

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this