Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

Emmanuel Callens; Edy Abou-Hamad; Nassima Riache; Jean-Marie Basset

doi:10.1039/c4cc00286e

Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

Emmanuel Callens, Edy Abou-Hamad, Nassima Riache, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. © 2014 the Partner Organisations.

Original language	English (US)
Pages (from-to)	3982-3985
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	30
DOIs	https://doi.org/10.1039/c4cc00286e
State	Published - 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors thank Dr Manoja Samantaray and Dr Raju Dey for their contribution in the synthesis of the silica supported W-catalyst. Research leading to these results has received funding from the University of King Abdullah University of Science and Technology.

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

Access to Document

10.1039/c4cc00286e

Cite this

@article{61af6d1ae2d9469da94210285eb33b0a,

title = "Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species",

abstract = "Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. {\textcopyright} 2014 the Partner Organisations.",

author = "Emmanuel Callens and Edy Abou-Hamad and Nassima Riache and Jean-Marie Basset",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors thank Dr Manoja Samantaray and Dr Raju Dey for their contribution in the synthesis of the silica supported W-catalyst. Research leading to these results has received funding from the University of King Abdullah University of Science and Technology.",

year = "2014",

doi = "10.1039/c4cc00286e",

language = "English (US)",

volume = "50",

pages = "3982--3985",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "30",

}

TY - JOUR

T1 - Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

AU - Callens, Emmanuel

AU - Abou-Hamad, Edy

AU - Riache, Nassima

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors thank Dr Manoja Samantaray and Dr Raju Dey for their contribution in the synthesis of the silica supported W-catalyst. Research leading to these results has received funding from the University of King Abdullah University of Science and Technology.

PY - 2014

Y1 - 2014

N2 - Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. © 2014 the Partner Organisations.

AB - Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. © 2014 the Partner Organisations.

UR - http://hdl.handle.net/10754/563180

UR - http://xlink.rsc.org/?DOI=C4CC00286E

UR - http://www.scopus.com/inward/record.url?scp=85034328172&partnerID=8YFLogxK

U2 - 10.1039/c4cc00286e

DO - 10.1039/c4cc00286e

M3 - Article

C2 - 24609531

SN - 1359-7345

VL - 50

SP - 3982

EP - 3985

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this