Direct functionalization of nanodiamonds with maleimide

Omar El Tall; Yuanfang Hou; Edy Abou-Hamad; Inam Ul haq Raja; Mohamed N. Hedhili; Wei Peng; Remi Mahfouz; Osman Bakr; Pierre Beaujuge

doi:10.1021/cm500036x

Direct functionalization of nanodiamonds with maleimide

Omar El Tall, Yuanfang Hou, Edy Abou-Hamad, Inam Ul haq Raja, Mohamed N. Hedhili, Wei Peng, Remi Mahfouz, Osman Bakr, Pierre Beaujuge

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Diamond materials span a wide range of attractive physical properties, including large mechanical resistance, high thermal conductivity, and tunable optoelectronic behavior when suitably doped. Down to the nanoscale, embedded diamond nanoparticles find use in surface coatings and nanocomposites and are promising building elements in nanophotonic device engineering. The nature of the solubilizing substituents and specific functional groups appended to the nanodiamond surface defines the function of the nanoparticle and in turn its field of applicability. Synthetic nanodiamonds prepared by detonation protocols, so-called detonation diamond nanoparticles (DDNP), are composed of primary nanocrystals (2-10 nm) and their aggregates. A detailed experimental section can be found in the Supporting Information; the XRD analysis of the GDNP(800) precursor confirmed the integrity of the diamond core upon thermal annealing.

Original language	English (US)
Pages (from-to)	2766-2769
Number of pages	4
Journal	Chemistry of Materials
Volume	26
Issue number	9
DOIs	https://doi.org/10.1021/cm500036x
State	Published - Apr 21 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): FIC/2010/02
Acknowledgements: The authors acknowledge the financial support of the Office of Competitive Research Funds (OCRF) at King Abdullah University of Science and Technology (KAUST) under the "Competitive Research Grant" (CRG) program No. FIC/2010/02. The authors thank KAUST Analytical Core Laboratories for mass spectrometry and elemental analyses. OET thanks Dr. Clement Cabanetos for helpful discussions.

ASJC Scopus subject areas

Materials Chemistry
General Chemical Engineering
General Chemistry

Access to Document

10.1021/cm500036x

Cite this

@article{1b1012ffb8c34f7ab944b79d9ad4f976,

title = "Direct functionalization of nanodiamonds with maleimide",

abstract = "Diamond materials span a wide range of attractive physical properties, including large mechanical resistance, high thermal conductivity, and tunable optoelectronic behavior when suitably doped. Down to the nanoscale, embedded diamond nanoparticles find use in surface coatings and nanocomposites and are promising building elements in nanophotonic device engineering. The nature of the solubilizing substituents and specific functional groups appended to the nanodiamond surface defines the function of the nanoparticle and in turn its field of applicability. Synthetic nanodiamonds prepared by detonation protocols, so-called detonation diamond nanoparticles (DDNP), are composed of primary nanocrystals (2-10 nm) and their aggregates. A detailed experimental section can be found in the Supporting Information; the XRD analysis of the GDNP(800) precursor confirmed the integrity of the diamond core upon thermal annealing.",

author = "{El Tall}, Omar and Yuanfang Hou and Edy Abou-Hamad and Raja, {Inam Ul haq} and Hedhili, {Mohamed N.} and Wei Peng and Remi Mahfouz and Osman Bakr and Pierre Beaujuge",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/02 Acknowledgements: The authors acknowledge the financial support of the Office of Competitive Research Funds (OCRF) at King Abdullah University of Science and Technology (KAUST) under the {"}Competitive Research Grant{"} (CRG) program No. FIC/2010/02. The authors thank KAUST Analytical Core Laboratories for mass spectrometry and elemental analyses. OET thanks Dr. Clement Cabanetos for helpful discussions.",

year = "2014",

month = apr,

day = "21",

doi = "10.1021/cm500036x",

language = "English (US)",

volume = "26",

pages = "2766--2769",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Direct functionalization of nanodiamonds with maleimide

AU - El Tall, Omar

AU - Hou, Yuanfang

AU - Abou-Hamad, Edy

AU - Raja, Inam Ul haq

AU - Hedhili, Mohamed N.

AU - Peng, Wei

AU - Mahfouz, Remi

AU - Bakr, Osman

AU - Beaujuge, Pierre

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/02 Acknowledgements: The authors acknowledge the financial support of the Office of Competitive Research Funds (OCRF) at King Abdullah University of Science and Technology (KAUST) under the "Competitive Research Grant" (CRG) program No. FIC/2010/02. The authors thank KAUST Analytical Core Laboratories for mass spectrometry and elemental analyses. OET thanks Dr. Clement Cabanetos for helpful discussions.

PY - 2014/4/21

Y1 - 2014/4/21

N2 - Diamond materials span a wide range of attractive physical properties, including large mechanical resistance, high thermal conductivity, and tunable optoelectronic behavior when suitably doped. Down to the nanoscale, embedded diamond nanoparticles find use in surface coatings and nanocomposites and are promising building elements in nanophotonic device engineering. The nature of the solubilizing substituents and specific functional groups appended to the nanodiamond surface defines the function of the nanoparticle and in turn its field of applicability. Synthetic nanodiamonds prepared by detonation protocols, so-called detonation diamond nanoparticles (DDNP), are composed of primary nanocrystals (2-10 nm) and their aggregates. A detailed experimental section can be found in the Supporting Information; the XRD analysis of the GDNP(800) precursor confirmed the integrity of the diamond core upon thermal annealing.

AB - Diamond materials span a wide range of attractive physical properties, including large mechanical resistance, high thermal conductivity, and tunable optoelectronic behavior when suitably doped. Down to the nanoscale, embedded diamond nanoparticles find use in surface coatings and nanocomposites and are promising building elements in nanophotonic device engineering. The nature of the solubilizing substituents and specific functional groups appended to the nanodiamond surface defines the function of the nanoparticle and in turn its field of applicability. Synthetic nanodiamonds prepared by detonation protocols, so-called detonation diamond nanoparticles (DDNP), are composed of primary nanocrystals (2-10 nm) and their aggregates. A detailed experimental section can be found in the Supporting Information; the XRD analysis of the GDNP(800) precursor confirmed the integrity of the diamond core upon thermal annealing.

UR - http://hdl.handle.net/10754/563547

UR - https://pubs.acs.org/doi/10.1021/cm500036x

UR - http://www.scopus.com/inward/record.url?scp=84902349730&partnerID=8YFLogxK

U2 - 10.1021/cm500036x

DO - 10.1021/cm500036x

M3 - Article

SN - 0897-4756

VL - 26

SP - 2766

EP - 2769

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 9

ER -

Direct functionalization of nanodiamonds with maleimide

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this