Direct deposition of trivalent rhodium hydroxide nanoparticles onto a semiconducting layered calcium niobate for photocatalytic hydrogen evolution

Hideo Hata; Yoji Kobayashi; Vince Bojan; W. Justin Youngblood; Thomas E. Mallouk

doi:10.1021/nl072571w

Direct deposition of trivalent rhodium hydroxide nanoparticles onto a semiconducting layered calcium niobate for photocatalytic hydrogen evolution

Hideo Hata, Yoji Kobayashi, Vince Bojan, W. Justin Youngblood, Thomas E. Mallouk

Research output: Contribution to journal › Article › peer-review

135 Scopus citations

Abstract

Well-dispersed Rh(OH) 3 nanoparticles were deposited in the interlayer galleries of a Dion-Jacobson type layered perovskite (ACa 2Nb 3O 10: A = H or K). X-ray photoelectron spectra and ζ potential measurements suggest covalent bonding (Rh-O-Nb) between the nanoparticles and the niobate sheets. After calcination of Rh(OH) 3/KCa 2Nb 3O 10 at 350°C in air, interlayer Rh(OH) 3 nanoparticles were transformed to Rh 2O 3 and showed higher photocatalytic activity for hydrogen evolution using methanol as a sacrificial electron donor. © 2008 American Chemical Society.

Original language	English (US)
Pages (from-to)	794-799
Number of pages	6
Journal	Nano Letters
Volume	8
Issue number	3
DOIs	https://doi.org/10.1021/nl072571w
State	Published - Mar 1 2008
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2022-09-13

ASJC Scopus subject areas

Bioengineering
General Materials Science
General Chemistry
Mechanical Engineering
Condensed Matter Physics

Access to Document

10.1021/nl072571w

Cite this

@article{9a0bc366f7ec4b20b9859237ff614021,

title = "Direct deposition of trivalent rhodium hydroxide nanoparticles onto a semiconducting layered calcium niobate for photocatalytic hydrogen evolution",

abstract = "Well-dispersed Rh(OH) 3 nanoparticles were deposited in the interlayer galleries of a Dion-Jacobson type layered perovskite (ACa 2Nb 3O 10: A = H or K). X-ray photoelectron spectra and ζ potential measurements suggest covalent bonding (Rh-O-Nb) between the nanoparticles and the niobate sheets. After calcination of Rh(OH) 3/KCa 2Nb 3O 10 at 350°C in air, interlayer Rh(OH) 3 nanoparticles were transformed to Rh 2O 3 and showed higher photocatalytic activity for hydrogen evolution using methanol as a sacrificial electron donor. {\textcopyright} 2008 American Chemical Society.",

author = "Hideo Hata and Yoji Kobayashi and Vince Bojan and {Justin Youngblood}, W. and Mallouk, {Thomas E.}",

note = "Generated from Scopus record by KAUST IRTS on 2022-09-13",

year = "2008",

month = mar,

day = "1",

doi = "10.1021/nl072571w",

language = "English (US)",

volume = "8",

pages = "794--799",

journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Direct deposition of trivalent rhodium hydroxide nanoparticles onto a semiconducting layered calcium niobate for photocatalytic hydrogen evolution

AU - Hata, Hideo

AU - Kobayashi, Yoji

AU - Bojan, Vince

AU - Justin Youngblood, W.

AU - Mallouk, Thomas E.

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-13

PY - 2008/3/1

Y1 - 2008/3/1

N2 - Well-dispersed Rh(OH) 3 nanoparticles were deposited in the interlayer galleries of a Dion-Jacobson type layered perovskite (ACa 2Nb 3O 10: A = H or K). X-ray photoelectron spectra and ζ potential measurements suggest covalent bonding (Rh-O-Nb) between the nanoparticles and the niobate sheets. After calcination of Rh(OH) 3/KCa 2Nb 3O 10 at 350°C in air, interlayer Rh(OH) 3 nanoparticles were transformed to Rh 2O 3 and showed higher photocatalytic activity for hydrogen evolution using methanol as a sacrificial electron donor. © 2008 American Chemical Society.

AB - Well-dispersed Rh(OH) 3 nanoparticles were deposited in the interlayer galleries of a Dion-Jacobson type layered perovskite (ACa 2Nb 3O 10: A = H or K). X-ray photoelectron spectra and ζ potential measurements suggest covalent bonding (Rh-O-Nb) between the nanoparticles and the niobate sheets. After calcination of Rh(OH) 3/KCa 2Nb 3O 10 at 350°C in air, interlayer Rh(OH) 3 nanoparticles were transformed to Rh 2O 3 and showed higher photocatalytic activity for hydrogen evolution using methanol as a sacrificial electron donor. © 2008 American Chemical Society.

UR - https://pubs.acs.org/doi/10.1021/nl072571w

UR - http://www.scopus.com/inward/record.url?scp=43149089133&partnerID=8YFLogxK

U2 - 10.1021/nl072571w

DO - 10.1021/nl072571w

M3 - Article

SN - 1530-6984

VL - 8

SP - 794

EP - 799

JO - Nano Letters

JF - Nano Letters

IS - 3

ER -

Direct deposition of trivalent rhodium hydroxide nanoparticles onto a semiconducting layered calcium niobate for photocatalytic hydrogen evolution

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this