Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/ Z Selectivity Controlled by tert-Butoxide

Fei Xue; Xiaolu Song; Ting Ting Lin; Kristin Munkerup; Saad Fahad Albawardi; Kuo Wei Huang; T. S.Andy Hor; Jin Zhao

doi:10.1021/acsomega.8b00539

Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/ Z Selectivity Controlled by tert-Butoxide

Fei Xue, Xiaolu Song, Ting Ting Lin, Kristin Munkerup, Saad Fahad Albawardi, Kuo Wei Huang^*, T. S.Andy Hor, Jin Zhao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KO^tBu or NaO^tBu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed.

Original language	English (US)
Pages (from-to)	5071-5077
Number of pages	7
Journal	ACS OMEGA
Volume	3
Issue number	5
DOIs	https://doi.org/10.1021/acsomega.8b00539
State	Published - May 9 2018

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Publisher Copyright:
© 2018 American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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@article{2a25868c34f24b63915891ad3616201f,

title = "Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/ Z Selectivity Controlled by tert-Butoxide",

abstract = "The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KOtBu or NaOtBu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed.",

author = "Fei Xue and Xiaolu Song and Lin, \{Ting Ting\} and Kristin Munkerup and Albawardi, \{Saad Fahad\} and Huang, \{Kuo Wei\} and Hor, \{T. S.Andy\} and Jin Zhao",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = may,

day = "9",

doi = "10.1021/acsomega.8b00539",

language = "English (US)",

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T1 - Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/ Z Selectivity Controlled by tert-Butoxide

AU - Xue, Fei

AU - Song, Xiaolu

AU - Lin, Ting Ting

AU - Munkerup, Kristin

AU - Albawardi, Saad Fahad

AU - Huang, Kuo Wei

AU - Hor, T. S.Andy

AU - Zhao, Jin

PY - 2018/5/9

Y1 - 2018/5/9

N2 - The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KOtBu or NaOtBu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed.

AB - The catalytic activity of iron(II) complexes with functionalized amine-pyrazolyl tripodal ligands toward dimerization of terminal alkynes in the presence a base (KOtBu or NaOtBu) has been studied. An unusual E/Z selectivity of the reaction determined by tert-butoxide was observed.

UR - http://www.scopus.com/inward/record.url?scp=85046884282&partnerID=8YFLogxK

U2 - 10.1021/acsomega.8b00539

DO - 10.1021/acsomega.8b00539

M3 - Article

AN - SCOPUS:85046884282

SN - 2470-1343

VL - 3

SP - 5071

EP - 5077

JO - ACS OMEGA

JF - ACS OMEGA

IS - 5

ER -

Dimerization of Terminal Aryl Alkynes Catalyzed by Iron(II) Amine-Pyrazolyl Tripodal Complexes with E/ Z Selectivity Controlled by tert-Butoxide

Abstract

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