Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing

Nikita Kulachenkov; Marina Barsukova; Pavel Alekseevskiy; Aleksandr A. Sapianik; Maxim Sergeev; Andrei Yankin; Andrei A. Krasilin; Semyon Bachinin; Sergei Shipilovskikh; Petr Poturaev; Natalia Medvedeva; Ekaterina Denislamova; Pavel S. Zelenovskiy; Vladimir V. Shilovskikh; Yuliya Kenzhebayeva; Anastasiia Efimova; Alexander S. Novikov; Artem Lunev; Vladimir P. Fedin; Valentin A. Milichko

doi:10.1021/acs.nanolett.2c01770

Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing

Nikita Kulachenkov^*, Marina Barsukova, Pavel Alekseevskiy, Aleksandr A. Sapianik, Maxim Sergeev, Andrei Yankin, Andrei A. Krasilin, Semyon Bachinin, Sergei Shipilovskikh, Petr Poturaev, Natalia Medvedeva, Ekaterina Denislamova, Pavel S. Zelenovskiy, Vladimir V. Shilovskikh, Yuliya Kenzhebayeva, Anastasiia Efimova, Alexander S. Novikov, Artem Lunev, Vladimir P. Fedin, Valentin A. Milichko^*

^*Corresponding author for this work

King Abdullah University of Science and Technology

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl₂] and [Cu(bImB)₂Cl₂] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s^-1for 1D and 2D CPs, respectively. The endurance over 10³cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.

Original language	English (US)
Pages (from-to)	6972-6981
Number of pages	10
Journal	Nano Letters
Volume	22
Issue number	17
DOIs	https://doi.org/10.1021/acs.nanolett.2c01770
State	Published - Sep 14 2022

Bibliographical note

Funding Information:
V.A.M. acknowledges financial support from the Russian Science Foundation (Project “Metal-organic frameworks: New class of crystals for data storage and processing” No. 19-79-10241) for optical experiments. P.S.Z. is grateful to the Ural Center for Shared Use “Modern nanotechnology” Ural Federal University (Reg. numb. 2968) supported by the Ministry of Science and Higher Education of the Russian Federation (Projec numb. 075-15-2021-677). The instrumental resources were partly provided by the the Centre for X-ray Diffraction Studies and Geomodel Resource Center of Saint Petersburg State University. The authors acknowledge A. Potapov (Nikolaev Institute of Inorganic Chemistry SB RAS, Russia) for synthesis support, Bartłomiej M. Szyja (Faculty of Chemistry, Wrocław University of Science and Technology, Wrocław, Poland), and Evgeny A. Pidko (Inorganic Systems Engineering Group, Department of Chemical Engineering, Delft University of Technology, The Netherlands) and supercomputer facilities from NWO Domain Science for their contribution to numerical modeling. The research was supported by Priority 2030 Federal Academic Leadership Program (A.S.N. is grateful to the RUDN University Strategic Academic Leadership Program, V.A.M. is grateful to ITMO University Strategic Academic Leadership Program).

Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.

Keywords

Coordination polymers
data processing
flexibility
in situ spectroscopy
low-dimensional structures
structural transformation

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

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10.1021/acs.nanolett.2c01770

Cite this

Kulachenkov, N., Barsukova, M., Alekseevskiy, P., Sapianik, A. A., Sergeev, M., Yankin, A., Krasilin, A. A., Bachinin, S., Shipilovskikh, S., Poturaev, P., Medvedeva, N., Denislamova, E., Zelenovskiy, P. S., Shilovskikh, V. V., Kenzhebayeva, Y., Efimova, A., Novikov, A. S., Lunev, A., Fedin, V. P., & Milichko, V. A. (2022). Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing. Nano Letters, 22(17), 6972-6981. https://doi.org/10.1021/acs.nanolett.2c01770

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title = "Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing",

abstract = "A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1for 1D and 2D CPs, respectively. The endurance over 103cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.",

keywords = "Coordination polymers, data processing, flexibility, in situ spectroscopy, low-dimensional structures, structural transformation",

author = "Nikita Kulachenkov and Marina Barsukova and Pavel Alekseevskiy and Sapianik, {Aleksandr A.} and Maxim Sergeev and Andrei Yankin and Krasilin, {Andrei A.} and Semyon Bachinin and Sergei Shipilovskikh and Petr Poturaev and Natalia Medvedeva and Ekaterina Denislamova and Zelenovskiy, {Pavel S.} and Shilovskikh, {Vladimir V.} and Yuliya Kenzhebayeva and Anastasiia Efimova and Novikov, {Alexander S.} and Artem Lunev and Fedin, {Vladimir P.} and Milichko, {Valentin A.}",

note = "Funding Information: V.A.M. acknowledges financial support from the Russian Science Foundation (Project “Metal-organic frameworks: New class of crystals for data storage and processing” No. 19-79-10241) for optical experiments. P.S.Z. is grateful to the Ural Center for Shared Use “Modern nanotechnology” Ural Federal University (Reg. numb. 2968) supported by the Ministry of Science and Higher Education of the Russian Federation (Projec numb. 075-15-2021-677). The instrumental resources were partly provided by the the Centre for X-ray Diffraction Studies and Geomodel Resource Center of Saint Petersburg State University. The authors acknowledge A. Potapov (Nikolaev Institute of Inorganic Chemistry SB RAS, Russia) for synthesis support, Bart{\l}omiej M. Szyja (Faculty of Chemistry, Wroc{\l}aw University of Science and Technology, Wroc{\l}aw, Poland), and Evgeny A. Pidko (Inorganic Systems Engineering Group, Department of Chemical Engineering, Delft University of Technology, The Netherlands) and supercomputer facilities from NWO Domain Science for their contribution to numerical modeling. The research was supported by Priority 2030 Federal Academic Leadership Program (A.S.N. is grateful to the RUDN University Strategic Academic Leadership Program, V.A.M. is grateful to ITMO University Strategic Academic Leadership Program). Publisher Copyright: {\textcopyright} 2022 American Chemical Society. All rights reserved.",

year = "2022",

month = sep,

day = "14",

doi = "10.1021/acs.nanolett.2c01770",

language = "English (US)",

volume = "22",

pages = "6972--6981",

journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "17",

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Kulachenkov, N, Barsukova, M, Alekseevskiy, P, Sapianik, AA, Sergeev, M, Yankin, A, Krasilin, AA, Bachinin, S, Shipilovskikh, S, Poturaev, P, Medvedeva, N, Denislamova, E, Zelenovskiy, PS, Shilovskikh, VV, Kenzhebayeva, Y, Efimova, A, Novikov, AS, Lunev, A, Fedin, VP & Milichko, VA 2022, 'Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing', Nano Letters, vol. 22, no. 17, pp. 6972-6981. https://doi.org/10.1021/acs.nanolett.2c01770

TY - JOUR

T1 - Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing

AU - Kulachenkov, Nikita

AU - Barsukova, Marina

AU - Alekseevskiy, Pavel

AU - Sapianik, Aleksandr A.

AU - Sergeev, Maxim

AU - Yankin, Andrei

AU - Krasilin, Andrei A.

AU - Bachinin, Semyon

AU - Shipilovskikh, Sergei

AU - Poturaev, Petr

AU - Medvedeva, Natalia

AU - Denislamova, Ekaterina

AU - Zelenovskiy, Pavel S.

AU - Shilovskikh, Vladimir V.

AU - Kenzhebayeva, Yuliya

AU - Efimova, Anastasiia

AU - Novikov, Alexander S.

AU - Lunev, Artem

AU - Fedin, Vladimir P.

AU - Milichko, Valentin A.

N1 - Funding Information: V.A.M. acknowledges financial support from the Russian Science Foundation (Project “Metal-organic frameworks: New class of crystals for data storage and processing” No. 19-79-10241) for optical experiments. P.S.Z. is grateful to the Ural Center for Shared Use “Modern nanotechnology” Ural Federal University (Reg. numb. 2968) supported by the Ministry of Science and Higher Education of the Russian Federation (Projec numb. 075-15-2021-677). The instrumental resources were partly provided by the the Centre for X-ray Diffraction Studies and Geomodel Resource Center of Saint Petersburg State University. The authors acknowledge A. Potapov (Nikolaev Institute of Inorganic Chemistry SB RAS, Russia) for synthesis support, Bartłomiej M. Szyja (Faculty of Chemistry, Wrocław University of Science and Technology, Wrocław, Poland), and Evgeny A. Pidko (Inorganic Systems Engineering Group, Department of Chemical Engineering, Delft University of Technology, The Netherlands) and supercomputer facilities from NWO Domain Science for their contribution to numerical modeling. The research was supported by Priority 2030 Federal Academic Leadership Program (A.S.N. is grateful to the RUDN University Strategic Academic Leadership Program, V.A.M. is grateful to ITMO University Strategic Academic Leadership Program). Publisher Copyright: © 2022 American Chemical Society. All rights reserved.

PY - 2022/9/14

Y1 - 2022/9/14

N2 - A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1for 1D and 2D CPs, respectively. The endurance over 103cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.

AB - A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s-1for 1D and 2D CPs, respectively. The endurance over 103cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.

KW - Coordination polymers

KW - data processing

KW - flexibility

KW - in situ spectroscopy

KW - low-dimensional structures

KW - structural transformation

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U2 - 10.1021/acs.nanolett.2c01770

DO - 10.1021/acs.nanolett.2c01770

M3 - Article

C2 - 36018814

AN - SCOPUS:85137291257

SN - 1530-6984

VL - 22

SP - 6972

EP - 6981

JO - Nano Letters

JF - Nano Letters

IS - 17

ER -

Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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