Diketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistors

Catherine K. Kanimozhi; Nir Yaacobi-Gross; Kang Wei Chou; Aram Amassian; Thomas D. Anthopoulos; Satish P. Patil

doi:10.1021/ja308211n

Diketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistors

Catherine K. Kanimozhi, Nir Yaacobi-Gross, Kang Wei Chou, Aram Amassian, Thomas D. Anthopoulos, Satish P. Patil

Research output: Contribution to journal › Article › peer-review

353 Scopus citations

Abstract

In this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to ∼1100 nm) and field-effect electron mobility values of >1 cm 2 V -1 s -1. The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics. © 2012 American Chemical Society.

Original language	English (US)
Pages (from-to)	16532-16535
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	40
DOIs	https://doi.org/10.1021/ja308211n
State	Published - Oct 2012

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors acknowledge financial support from the Department of Science and Technology, India through the Indo-UK Apex Program and Ministry of Communication and Information Technology under a grant for the Centre of Excellence in Nanoelectronics, Phase II. We thank our colleagues Dr. Mallari Naik and Dr. N. Venkatramaiah for the TD-DFT calculations and support. We are grateful to Anke Helfer for GPC measurements. T.D.A. and N.Y.G. are grateful to the Engineering and Physical Sciences Research Council (EPSRC) (Grant EP/J001473/1) and the European Research Council (ERC) for financial support. Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a Directorate of SLAC National Accelerator Laboratory and an Office of Science User Facility operated for the U.S. Department of Energy Office of Science by Stanford University.

ASJC Scopus subject areas

Biochemistry
Colloid and Surface Chemistry
General Chemistry
Catalysis

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title = "Diketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistors",

abstract = "In this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to ∼1100 nm) and field-effect electron mobility values of >1 cm 2 V -1 s -1. The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics. {\textcopyright} 2012 American Chemical Society.",

author = "Kanimozhi, {Catherine K.} and Nir Yaacobi-Gross and Chou, {Kang Wei} and Aram Amassian and Anthopoulos, {Thomas D.} and Patil, {Satish P.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors acknowledge financial support from the Department of Science and Technology, India through the Indo-UK Apex Program and Ministry of Communication and Information Technology under a grant for the Centre of Excellence in Nanoelectronics, Phase II. We thank our colleagues Dr. Mallari Naik and Dr. N. Venkatramaiah for the TD-DFT calculations and support. We are grateful to Anke Helfer for GPC measurements. T.D.A. and N.Y.G. are grateful to the Engineering and Physical Sciences Research Council (EPSRC) (Grant EP/J001473/1) and the European Research Council (ERC) for financial support. Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a Directorate of SLAC National Accelerator Laboratory and an Office of Science User Facility operated for the U.S. Department of Energy Office of Science by Stanford University.",

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AU - Chou, Kang Wei

AU - Amassian, Aram

AU - Anthopoulos, Thomas D.

AU - Patil, Satish P.

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N2 - In this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to ∼1100 nm) and field-effect electron mobility values of >1 cm 2 V -1 s -1. The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics. © 2012 American Chemical Society.

AB - In this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to ∼1100 nm) and field-effect electron mobility values of >1 cm 2 V -1 s -1. The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics. © 2012 American Chemical Society.

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Diketopyrrolopyrrole-diketopyrrolopyrrole-based conjugated copolymer for high-mobility organic field-effect transistors

Abstract

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