Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

Daven Foster; Pengchao Gao; Ziyun Zhang; Gellért Sipos; Alexandre N. Sobolev; Gareth Nealon; Laura Falivene; Luigi Cavallo; Reto Dorta

doi:10.1039/d0sc05884j

Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

Daven Foster, Pengchao Gao, Ziyun Zhang, Gellért Sipos, Alexandre N. Sobolev, Gareth Nealon, Laura Falivene, Luigi Cavallo, Reto Dorta

Research output: Contribution to journal › Article › peer-review

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Abstract

Chiral, cationic NHC–iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes.

Original language	English (US)
Journal	Chemical Science
DOIs	https://doi.org/10.1039/d0sc05884j
State	Published - Feb 4 2021

Bibliographical note

KAUST Repository Item: Exported on 2021-02-03
Acknowledgements: D. F. and P. G. thank UWA for a Research Training Postgraduate (RTP) Scholarship. G. S. thanks UWA for an International Postgraduate Research Scholarship (IPRS). R. D. thanks the Australian Research Council for generous funding (FT130101713).

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10.1039/d0sc05884j

https://repository.kaust.edu.sa/bitstream/10754/667177/1/design%20scope%20and%20mechanism.pdf

Cite this

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title = "Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes",

abstract = "Chiral, cationic NHC–iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes.",

author = "Daven Foster and Pengchao Gao and Ziyun Zhang and Gell{\'e}rt Sipos and Sobolev, {Alexandre N.} and Gareth Nealon and Laura Falivene and Luigi Cavallo and Reto Dorta",

note = "KAUST Repository Item: Exported on 2021-02-03 Acknowledgements: D. F. and P. G. thank UWA for a Research Training Postgraduate (RTP) Scholarship. G. S. thanks UWA for an International Postgraduate Research Scholarship (IPRS). R. D. thanks the Australian Research Council for generous funding (FT130101713).",

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doi = "10.1039/d0sc05884j",

language = "English (US)",

journal = "Chemical Science",

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publisher = "Royal Society of Chemistry",

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T1 - Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

AU - Foster, Daven

AU - Gao, Pengchao

AU - Zhang, Ziyun

AU - Sipos, Gellért

AU - Sobolev, Alexandre N.

AU - Nealon, Gareth

AU - Falivene, Laura

AU - Cavallo, Luigi

AU - Dorta, Reto

N1 - KAUST Repository Item: Exported on 2021-02-03 Acknowledgements: D. F. and P. G. thank UWA for a Research Training Postgraduate (RTP) Scholarship. G. S. thanks UWA for an International Postgraduate Research Scholarship (IPRS). R. D. thanks the Australian Research Council for generous funding (FT130101713).

PY - 2021/2/4

Y1 - 2021/2/4

N2 - Chiral, cationic NHC–iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes.

AB - Chiral, cationic NHC–iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes.

UR - http://hdl.handle.net/10754/667177

UR - http://xlink.rsc.org/?DOI=D0SC05884J

U2 - 10.1039/d0sc05884j

DO - 10.1039/d0sc05884j

M3 - Article

C2 - 34163649

SN - 2041-6520

JO - Chemical Science

JF - Chemical Science

ER -

Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

Abstract

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CCDC 2022610: Experimental Crystal Structure Determination : (Ra,Ra,R,R)-(1,3-bis(2,7-dicyclohexylnaphthalen-1-yl)octahydro-1H-benzimidazol-2-ylidene)-chloro-(cycloocta-1,5-diene)-iridium

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Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

Abstract

Bibliographical note

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Other files and links

Fingerprint

Datasets

CCDC 2022610: Experimental Crystal Structure Determination : (Ra,Ra,R,R)-(1,3-bis(2,7-dicyclohexylnaphthalen-1-yl)octahydro-1H-benzimidazol-2-ylidene)-chloro-(cycloocta-1,5-diene)-iridium

Cite this