Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene

Damien Quémener; Valérie Héroguez; Yves Gnanou

doi:10.1002/pola.21370

Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene

Damien Quémener, Valérie Héroguez^*, Yves Gnanou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ring-opening metathesis polymerization of norbornene. Stable particles of polynorbornene could be generated in the 200-250 nm size range stabilized with a nonionic surfactant (poly-styrene-b-poly(ethylene oxide)).

Original language	English (US)
Pages (from-to)	2784-2793
Number of pages	10
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	44
Issue number	9
DOIs	https://doi.org/10.1002/pola.21370
State	Published - May 1 2006
Externally published	Yes

Keywords

Macromonomers
Miniemulsion polymerization
Ring-opening metathesis polymerization
Water-soluble carbene

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pola.21370

Cite this

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abstract = "Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ring-opening metathesis polymerization of norbornene. Stable particles of polynorbornene could be generated in the 200-250 nm size range stabilized with a nonionic surfactant (poly-styrene-b-poly(ethylene oxide)).",

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Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene. / Quémener, Damien; Héroguez, Valérie; Gnanou, Yves.
In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 44, No. 9, 01.05.2006, p. 2784-2793.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene

AU - Quémener, Damien

AU - Héroguez, Valérie

AU - Gnanou, Yves

PY - 2006/5/1

Y1 - 2006/5/1

N2 - Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ring-opening metathesis polymerization of norbornene. Stable particles of polynorbornene could be generated in the 200-250 nm size range stabilized with a nonionic surfactant (poly-styrene-b-poly(ethylene oxide)).

AB - Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ring-opening metathesis polymerization of norbornene. Stable particles of polynorbornene could be generated in the 200-250 nm size range stabilized with a nonionic surfactant (poly-styrene-b-poly(ethylene oxide)).

KW - Macromonomers

KW - Miniemulsion polymerization

KW - Ring-opening metathesis polymerization

KW - Water-soluble carbene

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

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Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene

Abstract

Keywords

ASJC Scopus subject areas

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