Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

Krishnamoorthy Muralirajan; Rajesh Kancherla; Magnus Rueping

doi:10.1002/anie.201808427

Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

Krishnamoorthy Muralirajan, Rajesh Kancherla, Magnus Rueping

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.

Original language	English (US)
Pages (from-to)	14787-14791
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	57
Issue number	45
DOIs	https://doi.org/10.1002/anie.201808427 https://doi.org/10.1002/ange.201808427
State	Published - Oct 11 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-04-23
Acknowledgements: The authors acknowledge KAUST for financial support. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC grant agreement number 617044 (SunCatChem).

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title = "Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis",

abstract = "Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.",

author = "Krishnamoorthy Muralirajan and Rajesh Kancherla and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2020-04-23 Acknowledgements: The authors acknowledge KAUST for financial support. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC grant agreement number 617044 (SunCatChem).",

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AU - Muralirajan, Krishnamoorthy

AU - Kancherla, Rajesh

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2020-04-23 Acknowledgements: The authors acknowledge KAUST for financial support. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC grant agreement number 617044 (SunCatChem).

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N2 - Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.

AB - Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.

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JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 45

ER -

Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

Abstract

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