Abstract
Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 14787-14791 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 57 |
| Issue number | 45 |
| DOIs | |
| State | Published - Nov 5 2018 |
Bibliographical note
Publisher Copyright:© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords
- C sulfonylation
- C(sp)-H functionalization
- aromatization
- dehydrogenation
- redox chemistry
ASJC Scopus subject areas
- General Chemistry
- Catalysis