Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes

Viktoriia Zubar, Aleksandra Brzozowska, Jan Sklyaruk, Magnus Rueping*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

A new manganese catalyzed heterocyclization of aminoalcohols has been accomplished. A wide range of heterocycles were synthesized, including 1,2,3,4-tetrahydroquinolines, dihydroquinolinones, and 2,3,4,5-tetrahydro-1H-benzo[b]azepines. The reaction is performed under mild reaction conditions using air and moisture stable manganese catalysts. The desired heterocycles were obtained in good to excellent yields.

Original languageEnglish (US)
Pages (from-to)1743-1747
Number of pages5
JournalOrganometallics
Volume41
Issue number14
DOIs
StatePublished - Jul 25 2022

Bibliographical note

Publisher Copyright:
© 2022 American Chemical Society.

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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