Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes

Viktoriia Zubar; Aleksandra Brzozowska; Jan Sklyaruk; Magnus Rueping

doi:10.1021/acs.organomet.2c00027

Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes

Viktoriia Zubar, Aleksandra Brzozowska, Jan Sklyaruk, Magnus Rueping^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A new manganese catalyzed heterocyclization of aminoalcohols has been accomplished. A wide range of heterocycles were synthesized, including 1,2,3,4-tetrahydroquinolines, dihydroquinolinones, and 2,3,4,5-tetrahydro-1H-benzo[b]azepines. The reaction is performed under mild reaction conditions using air and moisture stable manganese catalysts. The desired heterocycles were obtained in good to excellent yields.

Original language	English (US)
Pages (from-to)	1743-1747
Number of pages	5
Journal	Organometallics
Volume	41
Issue number	14
DOIs	https://doi.org/10.1021/acs.organomet.2c00027
State	Published - Jul 25 2022

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Publisher Copyright:
© 2022 American Chemical Society.

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/acs.organomet.2c00027

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title = "Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes",

abstract = "A new manganese catalyzed heterocyclization of aminoalcohols has been accomplished. A wide range of heterocycles were synthesized, including 1,2,3,4-tetrahydroquinolines, dihydroquinolinones, and 2,3,4,5-tetrahydro-1H-benzo[b]azepines. The reaction is performed under mild reaction conditions using air and moisture stable manganese catalysts. The desired heterocycles were obtained in good to excellent yields.",

author = "Viktoriia Zubar and Aleksandra Brzozowska and Jan Sklyaruk and Magnus Rueping",

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T1 - Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes

AU - Zubar, Viktoriia

AU - Brzozowska, Aleksandra

AU - Sklyaruk, Jan

AU - Rueping, Magnus

PY - 2022/7/25

Y1 - 2022/7/25

N2 - A new manganese catalyzed heterocyclization of aminoalcohols has been accomplished. A wide range of heterocycles were synthesized, including 1,2,3,4-tetrahydroquinolines, dihydroquinolinones, and 2,3,4,5-tetrahydro-1H-benzo[b]azepines. The reaction is performed under mild reaction conditions using air and moisture stable manganese catalysts. The desired heterocycles were obtained in good to excellent yields.

AB - A new manganese catalyzed heterocyclization of aminoalcohols has been accomplished. A wide range of heterocycles were synthesized, including 1,2,3,4-tetrahydroquinolines, dihydroquinolinones, and 2,3,4,5-tetrahydro-1H-benzo[b]azepines. The reaction is performed under mild reaction conditions using air and moisture stable manganese catalysts. The desired heterocycles were obtained in good to excellent yields.

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U2 - 10.1021/acs.organomet.2c00027

DO - 10.1021/acs.organomet.2c00027

M3 - Article

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IS - 14

ER -

Dehydrogenative and Redox-Neutral N-Heterocyclization of Aminoalcohols Catalyzed by Manganese Pincer Complexes

Abstract

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ASJC Scopus subject areas

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