Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

Lulu Fan; Jiaqi Jia; Hong Hou; Quentin Lefebvre; Magnus Rueping

doi:10.1002/chem.201604452

Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

Lulu Fan, Jiaqi Jia, Hong Hou, Quentin Lefebvre, Magnus Rueping

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.

Original language	English (US)
Pages (from-to)	16437-16440
Number of pages	4
Journal	Chemistry - A European Journal
Volume	22
Issue number	46
DOIs	https://doi.org/10.1002/chem.201604452
State	Published - Oct 10 2016

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The research leading to these results has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. 617044 (SunCatChem).

Access to Document

10.1002/chem.201604452

Cite this

@article{4eac48eb753f498d96c9be49cb7c9b33,

title = "Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling",

abstract = "A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.",

author = "Lulu Fan and Jiaqi Jia and Hong Hou and Quentin Lefebvre and Magnus Rueping",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The research leading to these results has received funding from the European Research Council under the European Union{\textquoteright}s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. 617044 (SunCatChem).",

year = "2016",

month = oct,

day = "10",

doi = "10.1002/chem.201604452",

language = "English (US)",

volume = "22",

pages = "16437--16440",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "46",

}

TY - JOUR

T1 - Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

AU - Fan, Lulu

AU - Jia, Jiaqi

AU - Hou, Hong

AU - Lefebvre, Quentin

AU - Rueping, Magnus

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The research leading to these results has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. 617044 (SunCatChem).

PY - 2016/10/10

Y1 - 2016/10/10

N2 - A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.

AB - A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.

UR - http://hdl.handle.net/10754/622116

UR - http://onlinelibrary.wiley.com/doi/10.1002/chem.201604452/abstract

UR - http://www.scopus.com/inward/record.url?scp=84994016179&partnerID=8YFLogxK

U2 - 10.1002/chem.201604452

DO - 10.1002/chem.201604452

M3 - Article

C2 - 27661773

SN - 0947-6539

VL - 22

SP - 16437

EP - 16440

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 46

ER -

Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this