Crystal structure of metal-organic coordination polymers [Cu(bpy) 2(H2O)2](NO3)2·4. 5C2H5OH and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O

M. P. Yutkin; M. S. Zavakhina; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S002247661102017X

Crystal structure of metal-organic coordination polymers [Cu(bpy) ₂(H₂O)₂](NO₃)₂·4. 5C₂H₅OH and [Cu₂(bpy)(H₂O)(L-pha) ₂](NO₃)₂·H₂O

M. P. Yutkin^*, M. S. Zavakhina, D. G. Samsonenko, V. P. Fedin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Two metal-organic coordination polymers [Cu(bpy)₂(H ₂O)₂](NO₃)₂·4.5C ₂H₅OH (1) and [Cu₂(bpy)(H₂O)(L-pha) ₂](NO₃)₂·H₂O (2) (L-Hpha = L-phenylalanine, bpy = 4,4'-bipyridyl) are prepared by slow evaporation of an aqueous alcoholic solution of copper nitrate, L-phenylalanine, and 4,4'- bipyridyl. The structure and composition of the obtained compounds are determined by single crystal XRD. The framework of compound 1 is positively charged and forms two types of intersecting channels. Compound 2 is a homochiral metal-organic coordination polymer whose structure contains L-phenylalanine anions.

Original language	English (US)
Pages (from-to)	365-370
Number of pages	6
Journal	Journal of Structural Chemistry
Volume	52
Issue number	2
DOIs	https://doi.org/10.1134/S002247661102017X
State	Published - Apr 2011
Externally published	Yes

Bibliographical note

Funding Information:
Two types of MOCP crystals were produced by the interaction of copper(II) nitrate, 4,4′-bipyridyl, and L-phenylalanine amino acid in an aqueous solution. The structure and composition of MOCPs were determined by single crystal X-ray diffraction. The coordination framework of [Cu(bpy)2(H2O)2](NO3)2⋅4.5C2H5OH (1) is composed of alternating cations of copper and 4,4′-bipyridyl. The framework has two types of intersecting channels of 7×7 Å and 3×7 Å. The composition of compound [Cu2(bpy)(H2O)(L-pha)2](NO3)2⋅H2O (2) involves L-phenylalanine anions and is a homochiral MOCP. This work was supported by RFBR (project nos. 09-03-90414 and 09-03-12112).

Keywords

4,4'-bipyridyl
Chiral complexes
Copper
Crystal structure
Metal-organic frameworks
Phenylalanine
coordination polymers

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1134/S002247661102017X

Cite this

@article{6a22aafba921451fa7b42264c3687e39,

title = "Crystal structure of metal-organic coordination polymers [Cu(bpy) 2(H2O)2](NO3)2·4. 5C2H5OH and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O",

abstract = "Two metal-organic coordination polymers [Cu(bpy)2(H 2O)2](NO3)2·4.5C 2H5OH (1) and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O (2) (L-Hpha = L-phenylalanine, bpy = 4,4'-bipyridyl) are prepared by slow evaporation of an aqueous alcoholic solution of copper nitrate, L-phenylalanine, and 4,4'- bipyridyl. The structure and composition of the obtained compounds are determined by single crystal XRD. The framework of compound 1 is positively charged and forms two types of intersecting channels. Compound 2 is a homochiral metal-organic coordination polymer whose structure contains L-phenylalanine anions.",

keywords = "4,4'-bipyridyl, Chiral complexes, Copper, Crystal structure, Metal-organic frameworks, Phenylalanine, coordination polymers",

author = "Yutkin, {M. P.} and Zavakhina, {M. S.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

note = "Funding Information: Two types of MOCP crystals were produced by the interaction of copper(II) nitrate, 4,4′-bipyridyl, and L-phenylalanine amino acid in an aqueous solution. The structure and composition of MOCPs were determined by single crystal X-ray diffraction. The coordination framework of [Cu(bpy)2(H2O)2](NO3)2⋅4.5C2H5OH (1) is composed of alternating cations of copper and 4,4′-bipyridyl. The framework has two types of intersecting channels of 7×7 {\AA} and 3×7 {\AA}. The composition of compound [Cu2(bpy)(H2O)(L-pha)2](NO3)2⋅H2O (2) involves L-phenylalanine anions and is a homochiral MOCP. This work was supported by RFBR (project nos. 09-03-90414 and 09-03-12112).",

year = "2011",

month = apr,

doi = "10.1134/S002247661102017X",

language = "English (US)",

volume = "52",

pages = "365--370",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

}

TY - JOUR

T1 - Crystal structure of metal-organic coordination polymers [Cu(bpy) 2(H2O)2](NO3)2·4. 5C2H5OH and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O

AU - Yutkin, M. P.

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

N1 - Funding Information: Two types of MOCP crystals were produced by the interaction of copper(II) nitrate, 4,4′-bipyridyl, and L-phenylalanine amino acid in an aqueous solution. The structure and composition of MOCPs were determined by single crystal X-ray diffraction. The coordination framework of [Cu(bpy)2(H2O)2](NO3)2⋅4.5C2H5OH (1) is composed of alternating cations of copper and 4,4′-bipyridyl. The framework has two types of intersecting channels of 7×7 Å and 3×7 Å. The composition of compound [Cu2(bpy)(H2O)(L-pha)2](NO3)2⋅H2O (2) involves L-phenylalanine anions and is a homochiral MOCP. This work was supported by RFBR (project nos. 09-03-90414 and 09-03-12112).

PY - 2011/4

Y1 - 2011/4

N2 - Two metal-organic coordination polymers [Cu(bpy)2(H 2O)2](NO3)2·4.5C 2H5OH (1) and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O (2) (L-Hpha = L-phenylalanine, bpy = 4,4'-bipyridyl) are prepared by slow evaporation of an aqueous alcoholic solution of copper nitrate, L-phenylalanine, and 4,4'- bipyridyl. The structure and composition of the obtained compounds are determined by single crystal XRD. The framework of compound 1 is positively charged and forms two types of intersecting channels. Compound 2 is a homochiral metal-organic coordination polymer whose structure contains L-phenylalanine anions.

AB - Two metal-organic coordination polymers [Cu(bpy)2(H 2O)2](NO3)2·4.5C 2H5OH (1) and [Cu2(bpy)(H2O)(L-pha) 2](NO3)2·H2O (2) (L-Hpha = L-phenylalanine, bpy = 4,4'-bipyridyl) are prepared by slow evaporation of an aqueous alcoholic solution of copper nitrate, L-phenylalanine, and 4,4'- bipyridyl. The structure and composition of the obtained compounds are determined by single crystal XRD. The framework of compound 1 is positively charged and forms two types of intersecting channels. Compound 2 is a homochiral metal-organic coordination polymer whose structure contains L-phenylalanine anions.

KW - 4,4'-bipyridyl

KW - Chiral complexes

KW - Copper

KW - Crystal structure

KW - Metal-organic frameworks

KW - Phenylalanine

KW - coordination polymers

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U2 - 10.1134/S002247661102017X

DO - 10.1134/S002247661102017X

M3 - Article

AN - SCOPUS:80054717694

SN - 0022-4766

VL - 52

SP - 365

EP - 370

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 2

ER -