Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

Mohammed Haque; Bambar Davaasuren; Alexander Rothenberger; Tao Wu

doi:10.1107/S2056989016017904

Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

Mohammed Haque, Bambar Davaasuren, Alexander Rothenberger, Tao Wu

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.

Original language	English (US)
Pages (from-to)	1791-1793
Number of pages	3
Journal	Acta Crystallographica Section E Crystallographic Communications
Volume	72
Issue number	12
DOIs	https://doi.org/10.1107/S2056989016017904
State	Published - Nov 15 2016

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by the King Abdullah University of Science and Technology (KAUST).

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10.1107/S2056989016017904

https://repository.kaust.edu.sa/bitstream/10754/622059/1/wm5337.pdf

Cite this

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title = "Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide",

abstract = "The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12){\AA}. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.",

author = "Mohammed Haque and Bambar Davaasuren and Alexander Rothenberger and Tao Wu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the King Abdullah University of Science and Technology (KAUST).",

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doi = "10.1107/S2056989016017904",

language = "English (US)",

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T1 - Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

AU - Haque, Mohammed

AU - Davaasuren, Bambar

AU - Rothenberger, Alexander

AU - Wu, Tao

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by the King Abdullah University of Science and Technology (KAUST).

PY - 2016/11/15

Y1 - 2016/11/15

N2 - The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.

AB - The title salt, [Mn(C2H6OS)6]I4, is made up from discrete [Mn(DMSO)6]2+ (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I4 2- tetraiodide anions. The MnII ion in the cation, situated on a position with site symmetry -3., is octahedrally coordinated by O atoms of the DMSO molecule with an Mn - O distance of 2.1808(12)Å. The I4 2- anion contains a neutral I2 molecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetraiodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.

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EP - 1793

JO - Acta Crystallographica Section E Crystallographic Communications

JF - Acta Crystallographica Section E Crystallographic Communications

IS - 12

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Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

Abstract

Bibliographical note

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CCDC 1515632: Experimental Crystal Structure Determination : hexakis(dimethyl sulfoxide)-manganese(ii) tetraiodide

Cite this

Crystal structure of hexakis(dimethyl sulfoxide-κO)manganese(II) tetraiodide

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1515632: Experimental Crystal Structure Determination : hexakis(dimethyl sulfoxide)-manganese(ii) tetraiodide

Cite this