CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS

S. V. Cherezova; M. O. Barsukova; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476621060093

CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS

S. V. Cherezova, M. O. Barsukova, D. G. Samsonenko, V. P. Fedin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Abstract: Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc₂(HCOO)₂(OH)₂(bpydc)]·2H₂O (1) and [Sc(HCOO)(bdc)] (2), where bpydc^2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc^2– is terephthalate, HCOO^– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

Original language	English (US)
Pages (from-to)	897-904
Number of pages	8
Journal	Journal of Structural Chemistry
Volume	62
Issue number	6
DOIs	https://doi.org/10.1134/S0022476621060093
State	Published - Jun 2021

Bibliographical note

Funding Information:
The study was supported by the Russian Science Foundation (project No.19-73-00169).

Publisher Copyright:
© 2021, Pleiades Publishing, Ltd.

Keywords

2,2′-bipyridine-4,4′-dicarboxylic acid
metal-organic frameworks
scandium
terephthalic acid
XRD

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{40263a1f5b6f4f00a89a80b6e8f43d4f,

title = "CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS",

abstract = "Abstract: Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.",

keywords = "2,2′-bipyridine-4,4′-dicarboxylic acid, metal-organic frameworks, scandium, terephthalic acid, XRD",

author = "Cherezova, {S. V.} and Barsukova, {M. O.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

note = "Funding Information: The study was supported by the Russian Science Foundation (project No.19-73-00169). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = jun,

doi = "10.1134/S0022476621060093",

language = "English (US)",

volume = "62",

pages = "897--904",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Pleiades Publishing",

number = "6",

}

TY - JOUR

T1 - CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS

AU - Cherezova, S. V.

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

PY - 2021/6

Y1 - 2021/6

N2 - Abstract: Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

AB - Abstract: Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

KW - 2,2′-bipyridine-4,4′-dicarboxylic acid

KW - metal-organic frameworks

KW - scandium

KW - terephthalic acid

KW - XRD

UR - http://www.scopus.com/inward/record.url?scp=85111112183&partnerID=8YFLogxK

U2 - 10.1134/S0022476621060093

DO - 10.1134/S0022476621060093

M3 - Article

AN - SCOPUS:85111112183

SN - 0022-4766

VL - 62

SP - 897

EP - 904

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 6

ER -

CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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