Crystal network formation in organic solar cells

J. J. Dittmer*, R. Lazzaroni, Ph Leclère, P. Moretti, M. Granström, K. Petritsch, E. A. Marseglia, R. H. Friend, J. L. Brédas, H. Rost, A. B. Holmes

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

162 Scopus citations

Abstract

We have studied the effects of annealing on performance and morphology of photovoltaic devices using blends of two organic semiconductors: a conjugated polymer and a soluble perylene derivative. The efficiency of such photovoltaic cells has been determined. The effect of temperature on blend morphology has been investigated for actual device films. Annealing leads to the formation of micron size perylene crystals and an enhancement of the quantum efficiency. This enhancement has been attributed to the formation of an electron conducting perylene crystal network.

Original languageEnglish (US)
Pages (from-to)53-61
Number of pages9
JournalSolar Energy Materials and Solar Cells
Volume61
Issue number1
DOIs
StatePublished - Feb 15 2000
Externally publishedYes

Bibliographical note

Funding Information:
Financial support from the Friedrich Naumann foundation and the European Commission TMR (SELOA-Network and Marie Curie Fellowship) and Brite-Euram OSCA program is gratefully acknowledged. R.L. is grateful for funding from the Fonds National de la Recherche Scientifique, Belgium. We would also like to thank Peter Ho and Devin MacKenzie for useful discussions.

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films

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