Crosslinked organic/inorganic hybrid proton exchange polymeric membranes

Maria Luisa Di Vona; Debora Marani; Cadia D'Ottavi; Marcella Trombetta; Enrico Traversa; Isabelle Beurroies; Philippe Knauth; Silvia Licoccia

Crosslinked organic/inorganic hybrid proton exchange polymeric membranes

Maria Luisa Di Vona^*, Debora Marani, Cadia D'Ottavi, Marcella Trombetta, Enrico Traversa, Isabelle Beurroies, Philippe Knauth, Silvia Licoccia

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

Abstract

A general, efficient and experimentally simple method for the synthesis of covalently crosslinked class II hybrid polymers based on PolyEtherEtherKetone (PEEK) with a high degree of sulfonation (DS = 0.8) was performed. The synthetic strategy foreseen two steps: the first one, direct sulfonation, led to the introduction of sulfonic acid groups and to the formation of sulfone bridges among repeat units. The second step, lithiation and silylation, led to the formation of covalent bonds between the organic backbone and Si(OH) ₃ moieties. The materials were characterized by !H NMR Spectroscopy, ATR/FTIR Spectroscopy, Thermogravimetric Analysis (TGA) and Mass Spectrometry. Preliminary proton conduction measurements in dry conditions were performed. The introduction of silicon groups in the system improved thermal stability.

Original language	English (US)
Pages (from-to)	67-73
Number of pages	7
Journal	Materials Research Society Symposium Proceedings
Volume	885
State	Published - 2006
Externally published	Yes
Event	2005 MRS Fall Meeting - Boston, MA, United States Duration: Nov 28 2005 → Dec 1 2005

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

@article{78628c92537f4417ab8597605b436194,

title = "Crosslinked organic/inorganic hybrid proton exchange polymeric membranes",

abstract = "A general, efficient and experimentally simple method for the synthesis of covalently crosslinked class II hybrid polymers based on PolyEtherEtherKetone (PEEK) with a high degree of sulfonation (DS = 0.8) was performed. The synthetic strategy foreseen two steps: the first one, direct sulfonation, led to the introduction of sulfonic acid groups and to the formation of sulfone bridges among repeat units. The second step, lithiation and silylation, led to the formation of covalent bonds between the organic backbone and Si(OH) 3 moieties. The materials were characterized by !H NMR Spectroscopy, ATR/FTIR Spectroscopy, Thermogravimetric Analysis (TGA) and Mass Spectrometry. Preliminary proton conduction measurements in dry conditions were performed. The introduction of silicon groups in the system improved thermal stability.",

author = "{Di Vona}, {Maria Luisa} and Debora Marani and Cadia D'Ottavi and Marcella Trombetta and Enrico Traversa and Isabelle Beurroies and Philippe Knauth and Silvia Licoccia",

year = "2006",

language = "English (US)",

volume = "885",

pages = "67--73",

journal = "Materials Research Society Symposium Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "2005 MRS Fall Meeting ; Conference date: 28-11-2005 Through 01-12-2005",

}

TY - JOUR

T1 - Crosslinked organic/inorganic hybrid proton exchange polymeric membranes

AU - Di Vona, Maria Luisa

AU - Marani, Debora

AU - D'Ottavi, Cadia

AU - Trombetta, Marcella

AU - Traversa, Enrico

AU - Beurroies, Isabelle

AU - Knauth, Philippe

AU - Licoccia, Silvia

PY - 2006

Y1 - 2006

N2 - A general, efficient and experimentally simple method for the synthesis of covalently crosslinked class II hybrid polymers based on PolyEtherEtherKetone (PEEK) with a high degree of sulfonation (DS = 0.8) was performed. The synthetic strategy foreseen two steps: the first one, direct sulfonation, led to the introduction of sulfonic acid groups and to the formation of sulfone bridges among repeat units. The second step, lithiation and silylation, led to the formation of covalent bonds between the organic backbone and Si(OH) 3 moieties. The materials were characterized by !H NMR Spectroscopy, ATR/FTIR Spectroscopy, Thermogravimetric Analysis (TGA) and Mass Spectrometry. Preliminary proton conduction measurements in dry conditions were performed. The introduction of silicon groups in the system improved thermal stability.

AB - A general, efficient and experimentally simple method for the synthesis of covalently crosslinked class II hybrid polymers based on PolyEtherEtherKetone (PEEK) with a high degree of sulfonation (DS = 0.8) was performed. The synthetic strategy foreseen two steps: the first one, direct sulfonation, led to the introduction of sulfonic acid groups and to the formation of sulfone bridges among repeat units. The second step, lithiation and silylation, led to the formation of covalent bonds between the organic backbone and Si(OH) 3 moieties. The materials were characterized by !H NMR Spectroscopy, ATR/FTIR Spectroscopy, Thermogravimetric Analysis (TGA) and Mass Spectrometry. Preliminary proton conduction measurements in dry conditions were performed. The introduction of silicon groups in the system improved thermal stability.

UR - http://www.scopus.com/inward/record.url?scp=33747349800&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:33747349800

SN - 0272-9172

VL - 885

SP - 67

EP - 73

JO - Materials Research Society Symposium Proceedings

JF - Materials Research Society Symposium Proceedings

T2 - 2005 MRS Fall Meeting

Y2 - 28 November 2005 through 1 December 2005

ER -

Crosslinked organic/inorganic hybrid proton exchange polymeric membranes

Abstract

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this