Correlating metal poisoning with zeolite deactivation in an individual catalyst particle by chemical and phase-sensitive X-ray microscopy

Javier Ruiz-Martínez; Andrew M. Beale; Upakul Deka; Mathew G. O'Brien; Paul D. Quinn; J. Fred W. Mosselmans; Bert M. Weckhuysen

doi:10.1002/anie.201210030

Correlating metal poisoning with zeolite deactivation in an individual catalyst particle by chemical and phase-sensitive X-ray microscopy

Javier Ruiz-Martínez, Andrew M. Beale, Upakul Deka, Mathew G. O'Brien, Paul D. Quinn, J. Fred W. Mosselmans, Bert M. Weckhuysen

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Fluid catalytic cracking (FCC) is the main conversion process used in oil refineries. An X-ray microscopy method is used to show that metal poisoning and related structural changes in the zeolite active material lead to a non-uniform core-shell deactivation of FCC catalyst particles. The study links the detrimental effect of V and Ni poisoning with zeolite destruction and dealumination in a spatial manner within a single FCC catalyst particle. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	23
DOIs	https://doi.org/10.1002/anie.201210030
State	Published - Jun 3 2013
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2019-08-08

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@article{d22f1200b1d14eccb0f9c0df7b4394ef,

title = "Correlating metal poisoning with zeolite deactivation in an individual catalyst particle by chemical and phase-sensitive X-ray microscopy",

abstract = "Fluid catalytic cracking (FCC) is the main conversion process used in oil refineries. An X-ray microscopy method is used to show that metal poisoning and related structural changes in the zeolite active material lead to a non-uniform core-shell deactivation of FCC catalyst particles. The study links the detrimental effect of V and Ni poisoning with zeolite destruction and dealumination in a spatial manner within a single FCC catalyst particle. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

author = "Javier Ruiz-Mart{\'i}nez and Beale, {Andrew M.} and Upakul Deka and O'Brien, {Mathew G.} and Quinn, {Paul D.} and Mosselmans, {J. Fred W.} and Weckhuysen, {Bert M.}",

note = "Generated from Scopus record by KAUST IRTS on 2019-08-08",

year = "2013",

month = jun,

day = "3",

doi = "10.1002/anie.201210030",

language = "English (US)",

volume = "52",

journal = "Angewandte Chemie - International Edition",

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T1 - Correlating metal poisoning with zeolite deactivation in an individual catalyst particle by chemical and phase-sensitive X-ray microscopy

AU - Ruiz-Martínez, Javier

AU - Beale, Andrew M.

AU - Deka, Upakul

AU - O'Brien, Mathew G.

AU - Quinn, Paul D.

AU - Mosselmans, J. Fred W.

AU - Weckhuysen, Bert M.

N1 - Generated from Scopus record by KAUST IRTS on 2019-08-08

PY - 2013/6/3

Y1 - 2013/6/3

N2 - Fluid catalytic cracking (FCC) is the main conversion process used in oil refineries. An X-ray microscopy method is used to show that metal poisoning and related structural changes in the zeolite active material lead to a non-uniform core-shell deactivation of FCC catalyst particles. The study links the detrimental effect of V and Ni poisoning with zeolite destruction and dealumination in a spatial manner within a single FCC catalyst particle. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Fluid catalytic cracking (FCC) is the main conversion process used in oil refineries. An X-ray microscopy method is used to show that metal poisoning and related structural changes in the zeolite active material lead to a non-uniform core-shell deactivation of FCC catalyst particles. The study links the detrimental effect of V and Ni poisoning with zeolite destruction and dealumination in a spatial manner within a single FCC catalyst particle. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

UR - http://doi.wiley.com/10.1002/anie.201210030

U2 - 10.1002/anie.201210030

DO - 10.1002/anie.201210030

M3 - Article

SN - 1433-7851

VL - 52

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

ER -

Correlating metal poisoning with zeolite deactivation in an individual catalyst particle by chemical and phase-sensitive X-ray microscopy

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