Copper(II) camphorates with tunable pore size in metal-organic frameworks

D. N. Dybtsev; M. P. Yutkin; V. P. Fedin

doi:10.1007/s11172-009-0313-y

Copper(II) camphorates with tunable pore size in metal-organic frameworks

D. N. Dybtsev, M. P. Yutkin, V. P. Fedin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Three new homochiral metal-organic coordination polymers [Cu ₂camph₂dabco] · DMF · 2H₂O, [Cu₂camph₂bipy] · 3DMF · 2H₂O, and [Cu₂camph₂bpe] · 4DMF · 2H₂O (H₂camph is (+)-cam-phoric acid, bipy is 4,4′-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

Original language	English (US)
Pages (from-to)	2246-2249
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	58
Issue number	11
DOIs	https://doi.org/10.1007/s11172-009-0313-y
State	Published - 2009
Externally published	Yes

Keywords

Chiral structures
Coordination polymers
Copper(II) complexes
Frameworks
Powder X-ray diffraction

ASJC Scopus subject areas

General Chemistry

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10.1007/s11172-009-0313-y

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title = "Copper(II) camphorates with tunable pore size in metal-organic frameworks",

abstract = "Three new homochiral metal-organic coordination polymers [Cu 2camph2dabco] · DMF · 2H2O, [Cu2camph2bipy] · 3DMF · 2H2O, and [Cu2camph2bpe] · 4DMF · 2H2O (H2camph is (+)-cam-phoric acid, bipy is 4,4′-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.",

keywords = "Chiral structures, Coordination polymers, Copper(II) complexes, Frameworks, Powder X-ray diffraction",

author = "Dybtsev, {D. N.} and Yutkin, {M. P.} and Fedin, {V. P.}",

year = "2009",

doi = "10.1007/s11172-009-0313-y",

language = "English (US)",

volume = "58",

pages = "2246--2249",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "11",

}

TY - JOUR

T1 - Copper(II) camphorates with tunable pore size in metal-organic frameworks

AU - Dybtsev, D. N.

AU - Yutkin, M. P.

AU - Fedin, V. P.

PY - 2009

Y1 - 2009

N2 - Three new homochiral metal-organic coordination polymers [Cu 2camph2dabco] · DMF · 2H2O, [Cu2camph2bipy] · 3DMF · 2H2O, and [Cu2camph2bpe] · 4DMF · 2H2O (H2camph is (+)-cam-phoric acid, bipy is 4,4′-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

AB - Three new homochiral metal-organic coordination polymers [Cu 2camph2dabco] · DMF · 2H2O, [Cu2camph2bipy] · 3DMF · 2H2O, and [Cu2camph2bpe] · 4DMF · 2H2O (H2camph is (+)-cam-phoric acid, bipy is 4,4′-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

KW - Chiral structures

KW - Coordination polymers

KW - Copper(II) complexes

KW - Frameworks

KW - Powder X-ray diffraction

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U2 - 10.1007/s11172-009-0313-y

DO - 10.1007/s11172-009-0313-y

M3 - Article

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VL - 58

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JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 11

ER -

Copper(II) camphorates with tunable pore size in metal-organic frameworks

Abstract

Keywords

ASJC Scopus subject areas

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