Copper-mediated cleavage of disulfides by tertiary phosphines: A new route to As-S anions

Robert Langer; Weifeng Shi; Alexander Rothenberger

doi:10.1039/b610228j

Copper-mediated cleavage of disulfides by tertiary phosphines: A new route to As-S anions

Robert Langer, Weifeng Shi, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis of [(PhAs)₂(-S₂)(-S)] and its reactions to form novel Cu(i) complexes are reported, together with a new cleavage reaction of disulfides by Cu(i) thiolates and tertiary phosphines.

Original language	English (US)
Pages (from-to)	4435-4437
Number of pages	3
Journal	Dalton transactions
Issue number	37
DOIs	https://doi.org/10.1039/b610228j
State	Published - 2006
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/b610228j

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@article{1d52c5624b94422d9e8eb1a6288eabcb,

title = "Copper-mediated cleavage of disulfides by tertiary phosphines: A new route to As-S anions",

abstract = "The synthesis of [(PhAs)2(-S2)(-S)] and its reactions to form novel Cu(i) complexes are reported, together with a new cleavage reaction of disulfides by Cu(i) thiolates and tertiary phosphines.",

author = "Robert Langer and Weifeng Shi and Alexander Rothenberger",

year = "2006",

doi = "10.1039/b610228j",

language = "English (US)",

pages = "4435--4437",

journal = "Dalton transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "37",

}

TY - JOUR

T1 - Copper-mediated cleavage of disulfides by tertiary phosphines

T2 - A new route to As-S anions

AU - Langer, Robert

AU - Shi, Weifeng

AU - Rothenberger, Alexander

PY - 2006

Y1 - 2006

N2 - The synthesis of [(PhAs)2(-S2)(-S)] and its reactions to form novel Cu(i) complexes are reported, together with a new cleavage reaction of disulfides by Cu(i) thiolates and tertiary phosphines.

AB - The synthesis of [(PhAs)2(-S2)(-S)] and its reactions to form novel Cu(i) complexes are reported, together with a new cleavage reaction of disulfides by Cu(i) thiolates and tertiary phosphines.

UR - http://www.scopus.com/inward/record.url?scp=33748713490&partnerID=8YFLogxK

U2 - 10.1039/b610228j

DO - 10.1039/b610228j

M3 - Article

C2 - 16981016

AN - SCOPUS:33748713490

SN - 1477-9226

SP - 4435

EP - 4437

JO - Dalton transactions

JF - Dalton transactions

IS - 37

ER -

Copper-mediated cleavage of disulfides by tertiary phosphines: A new route to As-S anions

Abstract

ASJC Scopus subject areas

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