CoP Nanoparticles Combined with WSe2 Nanosheets: An Efficient Hybrid Catalyst for Electrocatalytic Hydrogen Evolution Reaction

Jiahui Qian; Zhen Li; Xiaomeng Guo; Yang Li; Wenchao Peng; Guoliang Zhang; Fengbao Zhang; Xiaobin Fan

doi:10.1021/acs.iecr.7b03537

CoP Nanoparticles Combined with WSe2 Nanosheets: An Efficient Hybrid Catalyst for Electrocatalytic Hydrogen Evolution Reaction

Jiahui Qian, Zhen Li, Xiaomeng Guo, Yang Li, Wenchao Peng, Guoliang Zhang, Fengbao Zhang, Xiaobin Fan

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Hydrogen (H2) is a clean and efficient energy carrier, and great efforts have been focused on developing new non-Pt electrocatalysts for the hydrogen evolution reaction (HER). In this study, CoP/WSe2 nanosheets hybrids were successfully prepared, and their potential as a new non-noble HER catalyst was evaluated. We found that all the hybrids showed higher catalytic activity than pure CoP and WSe2 nanosheets, suggesting their synergistic catalytic effect in the HER. Particularly, in 0.5 M H2SO4, the hybrid with an optimized CoP-to-WSe2 mass ratio of 1:1 has the highest current density of 102.9 mA/cm2 at 300 mV vs RHE and excellent long-term stability.

Original language	English (US)
Pages (from-to)	483-489
Number of pages	7
Journal	Industrial and Engineering Chemistry Research
Volume	57
Issue number	2
DOIs	https://doi.org/10.1021/acs.iecr.7b03537
State	Published - Jan 17 2018
Externally published	Yes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2023-09-20

ASJC Scopus subject areas

General Chemical Engineering
General Chemistry
Industrial and Manufacturing Engineering

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10.1021/acs.iecr.7b03537

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title = "CoP Nanoparticles Combined with WSe2 Nanosheets: An Efficient Hybrid Catalyst for Electrocatalytic Hydrogen Evolution Reaction",

abstract = "Hydrogen (H2) is a clean and efficient energy carrier, and great efforts have been focused on developing new non-Pt electrocatalysts for the hydrogen evolution reaction (HER). In this study, CoP/WSe2 nanosheets hybrids were successfully prepared, and their potential as a new non-noble HER catalyst was evaluated. We found that all the hybrids showed higher catalytic activity than pure CoP and WSe2 nanosheets, suggesting their synergistic catalytic effect in the HER. Particularly, in 0.5 M H2SO4, the hybrid with an optimized CoP-to-WSe2 mass ratio of 1:1 has the highest current density of 102.9 mA/cm2 at 300 mV vs RHE and excellent long-term stability.",

author = "Jiahui Qian and Zhen Li and Xiaomeng Guo and Yang Li and Wenchao Peng and Guoliang Zhang and Fengbao Zhang and Xiaobin Fan",

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doi = "10.1021/acs.iecr.7b03537",

language = "English (US)",

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T1 - CoP Nanoparticles Combined with WSe2 Nanosheets: An Efficient Hybrid Catalyst for Electrocatalytic Hydrogen Evolution Reaction

AU - Qian, Jiahui

AU - Li, Zhen

AU - Guo, Xiaomeng

AU - Li, Yang

AU - Peng, Wenchao

AU - Zhang, Guoliang

AU - Zhang, Fengbao

AU - Fan, Xiaobin

N1 - Generated from Scopus record by KAUST IRTS on 2023-09-20

PY - 2018/1/17

Y1 - 2018/1/17

N2 - Hydrogen (H2) is a clean and efficient energy carrier, and great efforts have been focused on developing new non-Pt electrocatalysts for the hydrogen evolution reaction (HER). In this study, CoP/WSe2 nanosheets hybrids were successfully prepared, and their potential as a new non-noble HER catalyst was evaluated. We found that all the hybrids showed higher catalytic activity than pure CoP and WSe2 nanosheets, suggesting their synergistic catalytic effect in the HER. Particularly, in 0.5 M H2SO4, the hybrid with an optimized CoP-to-WSe2 mass ratio of 1:1 has the highest current density of 102.9 mA/cm2 at 300 mV vs RHE and excellent long-term stability.

AB - Hydrogen (H2) is a clean and efficient energy carrier, and great efforts have been focused on developing new non-Pt electrocatalysts for the hydrogen evolution reaction (HER). In this study, CoP/WSe2 nanosheets hybrids were successfully prepared, and their potential as a new non-noble HER catalyst was evaluated. We found that all the hybrids showed higher catalytic activity than pure CoP and WSe2 nanosheets, suggesting their synergistic catalytic effect in the HER. Particularly, in 0.5 M H2SO4, the hybrid with an optimized CoP-to-WSe2 mass ratio of 1:1 has the highest current density of 102.9 mA/cm2 at 300 mV vs RHE and excellent long-term stability.

UR - https://pubs.acs.org/doi/10.1021/acs.iecr.7b03537

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DO - 10.1021/acs.iecr.7b03537

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VL - 57

SP - 483

EP - 489

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 2

ER -

CoP Nanoparticles Combined with WSe2 Nanosheets: An Efficient Hybrid Catalyst for Electrocatalytic Hydrogen Evolution Reaction

Abstract

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ASJC Scopus subject areas

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