Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes

Chao Guan; Yupeng Pan; Eleanor Pei Ling Ang; Jinsong Hu; Changguang Yao; Mei-Hui Huang; Huaifeng Li; Zhiping Lai; Kuo-Wei Huang

doi:10.1039/c8gc02186d

Conversion of CO₂ from air into formate using amines and phosphorus-nitrogen PN³P-Ru(ii) pincer complexes

Chao Guan, Yupeng Pan, Eleanor Pei Ling Ang, Jinsong Hu, Changguang Yao, Mei-Hui Huang, Huaifeng Li, Zhiping Lai, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Well-defined ruthenium(ii) PN³P pincer complexes were developed for the hydrogenation of carbon dioxide. Excellent product selectivity and catalytic activity with TOF (turnover frequency) and TON (turnover number) up to 13000 h^-1 and 33000, respectively, in a THF/H₂O biphasic system were achieved. Notably, effective conversion of carbon dioxide from air into formate was conducted in the presence of an amine, allowing easy product separation and catalyst recycling.

Original language	English (US)
Pages (from-to)	4201-4205
Number of pages	5
Journal	Green Chemistry
Volume	20
Issue number	18
DOIs	https://doi.org/10.1039/c8gc02186d
State	Published - 2018

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Publisher Copyright:
© The Royal Society of Chemistry 2018.

ASJC Scopus subject areas

Environmental Chemistry
Pollution

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10.1039/c8gc02186d

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title = "Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes",

abstract = "Well-defined ruthenium(ii) PN3P pincer complexes were developed for the hydrogenation of carbon dioxide. Excellent product selectivity and catalytic activity with TOF (turnover frequency) and TON (turnover number) up to 13000 h-1 and 33000, respectively, in a THF/H2O biphasic system were achieved. Notably, effective conversion of carbon dioxide from air into formate was conducted in the presence of an amine, allowing easy product separation and catalyst recycling.",

author = "Chao Guan and Yupeng Pan and Ang, {Eleanor Pei Ling} and Jinsong Hu and Changguang Yao and Mei-Hui Huang and Huaifeng Li and Zhiping Lai and Kuo-Wei Huang",

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year = "2018",

doi = "10.1039/c8gc02186d",

language = "English (US)",

volume = "20",

pages = "4201--4205",

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T1 - Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes

AU - Guan, Chao

AU - Pan, Yupeng

AU - Ang, Eleanor Pei Ling

AU - Hu, Jinsong

AU - Yao, Changguang

AU - Huang, Mei-Hui

AU - Li, Huaifeng

AU - Lai, Zhiping

AU - Huang, Kuo-Wei

PY - 2018

Y1 - 2018

N2 - Well-defined ruthenium(ii) PN3P pincer complexes were developed for the hydrogenation of carbon dioxide. Excellent product selectivity and catalytic activity with TOF (turnover frequency) and TON (turnover number) up to 13000 h-1 and 33000, respectively, in a THF/H2O biphasic system were achieved. Notably, effective conversion of carbon dioxide from air into formate was conducted in the presence of an amine, allowing easy product separation and catalyst recycling.

AB - Well-defined ruthenium(ii) PN3P pincer complexes were developed for the hydrogenation of carbon dioxide. Excellent product selectivity and catalytic activity with TOF (turnover frequency) and TON (turnover number) up to 13000 h-1 and 33000, respectively, in a THF/H2O biphasic system were achieved. Notably, effective conversion of carbon dioxide from air into formate was conducted in the presence of an amine, allowing easy product separation and catalyst recycling.

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U2 - 10.1039/c8gc02186d

DO - 10.1039/c8gc02186d

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SN - 1463-9262

VL - 20

SP - 4201

EP - 4205

JO - Green Chemistry

JF - Green Chemistry

IS - 18

ER -

Conversion of CO₂ from air into formate using amines and phosphorus-nitrogen PN³P-Ru(ii) pincer complexes

Abstract

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CCDC 1828207: Experimental Crystal Structure Determination : (mu-N,N'-pyridine-2,6-diylbis[P,P-diphenyl(phosphinous amide)])-dicarbonyl-dihydrido-bis(N,N'-(pyridine-2,6-diyl)bis[P,P-diphenyl(phosphinous amide)])-di-ruthenium chloride hydrogen carbonate unk

CCDC 1828209: Experimental Crystal Structure Determination : carbonyl-(N-{6-[(diphenylphosphanyl)amino]pyridin-2(1H)-ylidene}-P,P-diphenylphosphinous amidato)-hydrido-(triphenylphosphine)-ruthenium unknown solvate

Cite this

Conversion of CO2 from air into formate using amines and phosphorus-nitrogen PN3P-Ru(ii) pincer complexes

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1828207: Experimental Crystal Structure Determination : (mu-N,N'-pyridine-2,6-diylbis[P,P-diphenyl(phosphinous amide)])-dicarbonyl-dihydrido-bis(N,N'-(pyridine-2,6-diyl)bis[P,P-diphenyl(phosphinous amide)])-di-ruthenium chloride hydrogen carbonate unk

CCDC 1828209: Experimental Crystal Structure Determination : carbonyl-(N-{6-[(diphenylphosphanyl)amino]pyridin-2(1H)-ylidene}-P,P-diphenylphosphinous amidato)-hydrido-(triphenylphosphine)-ruthenium unknown solvate

Cite this

Conversion of CO₂ from air into formate using amines and phosphorus-nitrogen PN³P-Ru(ii) pincer complexes