Controlled/Living Free-Radical Polymerizationof Styrene and n-Butyl Acrylate in the Presence of a Novel Asymmetric Nitroxyl Radical

D. Benoit; S. Grimaldi; J. P. Finet; P. Tordo; M. Fontanille; Y. Gnanou

Controlled/Living Free-Radical Polymerizationof Styrene and n-Butyl Acrylate in the Presence of a Novel Asymmetric Nitroxyl Radical

D. Benoit, S. Grimaldi, J. P. Finet, P. Tordo, M. Fontanille, Y. Gnanou^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

A novel nitroxyl radical containing a diethyl phosphonate group in the β-position to the nitrogen atom has been used as radical scavenger in free radical polymerization. In the presence of this stable free-radical, styrene and n-butyl acrylate undergo controlled / «living» polymerization. The samples of polystyrene (PS) and poly (n-butyl acrylate) (PBuA) obtained in this way exhibit a narrow Poisson-type distribution of molar masses.

Original language	English (US)
Pages (from-to)	225-235
Number of pages	11
Journal	ACS Symposium Series
Volume	685
State	Published - 1998
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Cite this

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title = "Controlled/Living Free-Radical Polymerizationof Styrene and n-Butyl Acrylate in the Presence of a Novel Asymmetric Nitroxyl Radical",

abstract = "A novel nitroxyl radical containing a diethyl phosphonate group in the β-position to the nitrogen atom has been used as radical scavenger in free radical polymerization. In the presence of this stable free-radical, styrene and n-butyl acrylate undergo controlled / «living» polymerization. The samples of polystyrene (PS) and poly (n-butyl acrylate) (PBuA) obtained in this way exhibit a narrow Poisson-type distribution of molar masses.",

author = "D. Benoit and S. Grimaldi and Finet, {J. P.} and P. Tordo and M. Fontanille and Y. Gnanou",

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pages = "225--235",

journal = "ACS Symposium Series",

issn = "0097-6156",

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T1 - Controlled/Living Free-Radical Polymerizationof Styrene and n-Butyl Acrylate in the Presence of a Novel Asymmetric Nitroxyl Radical

AU - Benoit, D.

AU - Grimaldi, S.

AU - Finet, J. P.

AU - Tordo, P.

AU - Fontanille, M.

AU - Gnanou, Y.

PY - 1998

Y1 - 1998

N2 - A novel nitroxyl radical containing a diethyl phosphonate group in the β-position to the nitrogen atom has been used as radical scavenger in free radical polymerization. In the presence of this stable free-radical, styrene and n-butyl acrylate undergo controlled / «living» polymerization. The samples of polystyrene (PS) and poly (n-butyl acrylate) (PBuA) obtained in this way exhibit a narrow Poisson-type distribution of molar masses.

AB - A novel nitroxyl radical containing a diethyl phosphonate group in the β-position to the nitrogen atom has been used as radical scavenger in free radical polymerization. In the presence of this stable free-radical, styrene and n-butyl acrylate undergo controlled / «living» polymerization. The samples of polystyrene (PS) and poly (n-butyl acrylate) (PBuA) obtained in this way exhibit a narrow Poisson-type distribution of molar masses.

UR - http://www.scopus.com/inward/record.url?scp=0347611282&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0347611282

SN - 0097-6156

VL - 685

SP - 225

EP - 235

JO - ACS Symposium Series

JF - ACS Symposium Series

ER -

Controlled/Living Free-Radical Polymerizationof Styrene and n-Butyl Acrylate in the Presence of a Novel Asymmetric Nitroxyl Radical

Abstract

ASJC Scopus subject areas

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