Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand

Xiaofang Wang; Ming Xue; Gang Wu; Ying Pan; Shilun Qiu

doi:10.1016/j.inoche.2015.12.004

Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand

Xiaofang Wang, Ming Xue, Gang Wu, Ying Pan, Shilun Qiu

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Abstract

© 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 Å2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 Å2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.

Original language	English (US)
Pages (from-to)	31-34
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	64
DOIs	https://doi.org/10.1016/j.inoche.2015.12.004
State	Published - Feb 2016
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21471066, 21571076), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

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10.1016/j.inoche.2015.12.004

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title = "Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand",

abstract = "{\textcopyright} 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 {\AA}2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 {\AA}2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.",

author = "Xiaofang Wang and Ming Xue and Gang Wu and Ying Pan and Shilun Qiu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21471066, 21571076), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012). This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2016",

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doi = "10.1016/j.inoche.2015.12.004",

language = "English (US)",

volume = "64",

pages = "31--34",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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AU - Wang, Xiaofang

AU - Xue, Ming

AU - Wu, Gang

AU - Pan, Ying

AU - Qiu, Shilun

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009 Acknowledgements: This work was supported by National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21471066, 21571076), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009) and Ministry of Education, Science and Technology Development Center Project (20120061130012). This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2016/2

Y1 - 2016/2

N2 - © 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 Å2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 Å2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.

AB - © 2015 Elsevier B.V. All Rights Reserved. The self-assembly of a prominent ligand, 5-(4-(1H-tetrazolyl)phen)isophthalic acid (H3TZPI), with Zn2 +/Cu2 + centres generates two new MOFs, [Zn2(TZPI)(μ3-OH)(H2O)2]·2H2O (JUC-161) and [Cu(HTZPI)(μ2-H2O)0.5(H2O)1.5]·5(H2O) (JUC-162). JUC-161 exhibits fascinating three-dimensional structures containing rectangular channels with dimensions of 6.5 × 3.0 Å2, and JUC-162 displays 3D supramolecular structures with 12.5 × 14.6 Å2 hexagonal channels. The observed structural diversity in these frameworks is due to the two distinct coordinating moieties of the H3TZPI ligand. The photoluminescence of JUC-161 and the magnetic properties of JUC-162 are also measured at room temperature. Photoluminescence investigations reveal that JUC-161 displays a strong main emission spectrum peak at 388 nm. JUC-162 is found to exhibit an antiferromagnetic interaction between Cu2 + ions.

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U2 - 10.1016/j.inoche.2015.12.004

DO - 10.1016/j.inoche.2015.12.004

M3 - Article

SN - 1387-7003

VL - 64

SP - 31

EP - 34

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand

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