Conjugated microporous polymer membranes for light-gated ion transport

Zongyao Zhou, I. Chun Chen, Lubna M. Rehman, Ammar M. Aboalsaud, Digambar B. Shinde, Li Cao, Yuting Zhang, Zhiping Lai*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Inspired by the light-gated ion channels in cell membranes that play important roles in many biological activities, herein, we developed an artificial light-gated ion channel membrane out of conjugated microporous polymers. Through bottom-up design of the monomer molecular structure and by the electropolymerization method, the membrane pore size and thickness were precisely controlled on the molecular level. The obtained membrane exhibited uniform pore size and highly sensitive light-switchable response. The photoisomerization of the polymer chain resulted in a reversible “on and off” light control over the pore size and subsequently led to light-gated ion transport across the membrane for a series of ions including hydrogen, potassium, sodium, lithium, calcium, magnesium, and aluminum ions.

Original languageEnglish (US)
Article numbereabo2929
JournalSCIENCE ADVANCES
Volume8
Issue number24
DOIs
StatePublished - Jun 2022

Bibliographical note

Funding Information:
We thank C. Gu (South China University of Technology) and J. Liu (University of Science and Technology of China) for discussion in this work. The project was supported by King Abdullah University of Science and Technology (KAUST) under the competitive research grant URF/1/3769-01 and BAS/1/1375-01.

Publisher Copyright:
Copyright © 2022 The Authors, some rights reserved

ASJC Scopus subject areas

  • General

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