Co@NH2-MIL-125(Ti): Cobaloxime-derived metal-organic framework-based composite for light-driven H2 production

M. A. Nasalevich; R. Becker; E. V. Ramos-Fernandez; S. Castellanos; S. L. Veber; M. V. Fedin; F. Kapteijn; J. N.H. Reek; J. I. Van Der Vlugt; J. Gascon

doi:10.1039/c4ee02853h

Co@NH₂-MIL-125(Ti): Cobaloxime-derived metal-organic framework-based composite for light-driven H₂ production

M. A. Nasalevich, R. Becker, E. V. Ramos-Fernandez, S. Castellanos, S. L. Veber, M. V. Fedin, F. Kapteijn, J. N.H. Reek^*, J. I. Van Der Vlugt, J. Gascon

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

361 Scopus citations

Abstract

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH₂-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.

Original language	English (US)
Pages (from-to)	364-375
Number of pages	12
Journal	Energy and Environmental Science
Volume	8
Issue number	1
DOIs	https://doi.org/10.1039/c4ee02853h
State	Published - Jan 1 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 The Royal Society of Chemistry.

ASJC Scopus subject areas

Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Nuclear Energy and Engineering
Pollution

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c4ee02853h

Cite this

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abstract = "We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.",

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AU - Becker, R.

AU - Ramos-Fernandez, E. V.

AU - Castellanos, S.

AU - Veber, S. L.

AU - Fedin, M. V.

AU - Kapteijn, F.

AU - Reek, J. N.H.

AU - Van Der Vlugt, J. I.

AU - Gascon, J.

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AB - We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.

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