TY - JOUR
T1 - Comparative studies of the geometric and electronic properties of 1,1-disubstituted-2,3,4,5-tetraphenylsiloles and 1,1,2,2-tetramethyl-3,4,5,6- tetraphenyl-1,2-disila-3,5-cyclohexadiene
AU - Zhan, Xiaowei
AU - Risko, Chad
AU - Korlyukov, Alexander
AU - Sena, Francis
AU - Timofeeva, Tatiana V.
AU - Antipin, Mikhail Yu
AU - Barlow, Stephen
AU - Brédas, Jean Luc
AU - Marder, Seth R.
PY - 2006
Y1 - 2006
N2 - We present an experimental and density functional theory comparison of the geometric structure, electronic characteristics and optical properties of 1,1-dimethyl-2,3,4,5-tetraphenylsilole (I), 1,1-(propane-1,3-diyl)-2,3,4,5- tetraphenylsilole (II), 1,1-dimethoxy-2,3,4,5-tetraphenylsilole (III) and 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,5-cyclohexadiene (IV). The molecular structures of II-IV have been determined using X-ray crystallography and are compared to the previously reported structure of I. Many characteristics of IV are significantly different from those of I-III, due to the presence of the additional silicon atom. In contrast to I-III, which have planar central rings, IV has a non-planar ring conformation due to the presence of two approximately tetrahedrally coordinated silicon atoms. Cyclic voltammetry suggests that I-III are reduced at similar potentials to that for tris(8-hydroquinolinato)aluminium and that IV is more readily oxidizable than I-III. Additionally, while IV is non-emissive in both solution and the solid state, the three siloles are fluorescent in the solid state. For the four compounds, we have calculated the intramolecular reorganization energies for electron- and hole-transfer reactions, ionization potentials and electron affinities.
AB - We present an experimental and density functional theory comparison of the geometric structure, electronic characteristics and optical properties of 1,1-dimethyl-2,3,4,5-tetraphenylsilole (I), 1,1-(propane-1,3-diyl)-2,3,4,5- tetraphenylsilole (II), 1,1-dimethoxy-2,3,4,5-tetraphenylsilole (III) and 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,5-cyclohexadiene (IV). The molecular structures of II-IV have been determined using X-ray crystallography and are compared to the previously reported structure of I. Many characteristics of IV are significantly different from those of I-III, due to the presence of the additional silicon atom. In contrast to I-III, which have planar central rings, IV has a non-planar ring conformation due to the presence of two approximately tetrahedrally coordinated silicon atoms. Cyclic voltammetry suggests that I-III are reduced at similar potentials to that for tris(8-hydroquinolinato)aluminium and that IV is more readily oxidizable than I-III. Additionally, while IV is non-emissive in both solution and the solid state, the three siloles are fluorescent in the solid state. For the four compounds, we have calculated the intramolecular reorganization energies for electron- and hole-transfer reactions, ionization potentials and electron affinities.
UR - http://www.scopus.com/inward/record.url?scp=33749341471&partnerID=8YFLogxK
U2 - 10.1039/b605343b
DO - 10.1039/b605343b
M3 - Article
AN - SCOPUS:33749341471
SN - 0959-9428
VL - 16
SP - 3814
EP - 3822
JO - Journal of Materials Chemistry
JF - Journal of Materials Chemistry
IS - 39
ER -